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Crystal structure of (E)-4-ethyl-2-(4-methoxybenzylidene)-3,4-dihydronaphthalen-1(2H)-one
In the title compound, C(20)H(20)O(2), the exocyclic C=C double bond has an E conformation. The ethyl substituent on the cyclohexanone ring is in an axial orientation. The cyclohexanone ring adopts a screw-boat conformation, with the methylene C atom and the C atom bearing the 4-methoxybenzyl...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459325/ https://www.ncbi.nlm.nih.gov/pubmed/26090211 http://dx.doi.org/10.1107/S205698901501004X |
Sumario: | In the title compound, C(20)H(20)O(2), the exocyclic C=C double bond has an E conformation. The ethyl substituent on the cyclohexanone ring is in an axial orientation. The cyclohexanone ring adopts a screw-boat conformation, with the methylene C atom and the C atom bearing the 4-methoxybenzylidene group displaced from the other atoms by 0.812 (1) and 0.334 (1) Å, respectively. The dihedral angle between the planes of the benzene rings is 42.20 (8)°. In the crystal, no directional interactions beyond van der Waals contacts are observed. |
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