Cargando…
Crystal structure of dimethyl 2,5-bis[(diphenoxyphosphoryl)oxy]cyclohexa-1,4-diene-1,4-dicarboxylate
In the title compound, C(34)H(30)O(12)P(2), which was synthesized via the esterification of dimethyl 2,5-dioxo-1,4-cyclohexanedicarboxylate with diphenyl chlorophosphate, the molecule has crystallographic inversion symmetry. The dihedral angles between the plane of the cyclohexa-1,4-diene rin...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459327/ https://www.ncbi.nlm.nih.gov/pubmed/26090189 http://dx.doi.org/10.1107/S2056989015008658 |
_version_ | 1782375204495818752 |
---|---|
author | Gao, Lei Ma, Zongshan Yan, Hong |
author_facet | Gao, Lei Ma, Zongshan Yan, Hong |
author_sort | Gao, Lei |
collection | PubMed |
description | In the title compound, C(34)H(30)O(12)P(2), which was synthesized via the esterification of dimethyl 2,5-dioxo-1,4-cyclohexanedicarboxylate with diphenyl chlorophosphate, the molecule has crystallographic inversion symmetry. The dihedral angles between the plane of the cyclohexa-1,4-diene ring and those of the two benzene rings of the substituent phosphate groups are 41.0 (1) and 89.5 (1)°, while that with the ester group is 3.1 (3)°. In the crystal, only weak intermolecular C—H⋯O hydrogen bonds are present. |
format | Online Article Text |
id | pubmed-4459327 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44593272015-06-18 Crystal structure of dimethyl 2,5-bis[(diphenoxyphosphoryl)oxy]cyclohexa-1,4-diene-1,4-dicarboxylate Gao, Lei Ma, Zongshan Yan, Hong Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(34)H(30)O(12)P(2), which was synthesized via the esterification of dimethyl 2,5-dioxo-1,4-cyclohexanedicarboxylate with diphenyl chlorophosphate, the molecule has crystallographic inversion symmetry. The dihedral angles between the plane of the cyclohexa-1,4-diene ring and those of the two benzene rings of the substituent phosphate groups are 41.0 (1) and 89.5 (1)°, while that with the ester group is 3.1 (3)°. In the crystal, only weak intermolecular C—H⋯O hydrogen bonds are present. International Union of Crystallography 2015-05-13 /pmc/articles/PMC4459327/ /pubmed/26090189 http://dx.doi.org/10.1107/S2056989015008658 Text en © Gao et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Gao, Lei Ma, Zongshan Yan, Hong Crystal structure of dimethyl 2,5-bis[(diphenoxyphosphoryl)oxy]cyclohexa-1,4-diene-1,4-dicarboxylate |
title | Crystal structure of dimethyl 2,5-bis[(diphenoxyphosphoryl)oxy]cyclohexa-1,4-diene-1,4-dicarboxylate |
title_full | Crystal structure of dimethyl 2,5-bis[(diphenoxyphosphoryl)oxy]cyclohexa-1,4-diene-1,4-dicarboxylate |
title_fullStr | Crystal structure of dimethyl 2,5-bis[(diphenoxyphosphoryl)oxy]cyclohexa-1,4-diene-1,4-dicarboxylate |
title_full_unstemmed | Crystal structure of dimethyl 2,5-bis[(diphenoxyphosphoryl)oxy]cyclohexa-1,4-diene-1,4-dicarboxylate |
title_short | Crystal structure of dimethyl 2,5-bis[(diphenoxyphosphoryl)oxy]cyclohexa-1,4-diene-1,4-dicarboxylate |
title_sort | crystal structure of dimethyl 2,5-bis[(diphenoxyphosphoryl)oxy]cyclohexa-1,4-diene-1,4-dicarboxylate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459327/ https://www.ncbi.nlm.nih.gov/pubmed/26090189 http://dx.doi.org/10.1107/S2056989015008658 |
work_keys_str_mv | AT gaolei crystalstructureofdimethyl25bisdiphenoxyphosphoryloxycyclohexa14diene14dicarboxylate AT mazongshan crystalstructureofdimethyl25bisdiphenoxyphosphoryloxycyclohexa14diene14dicarboxylate AT yanhong crystalstructureofdimethyl25bisdiphenoxyphosphoryloxycyclohexa14diene14dicarboxylate |