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Crystal structure of 1,13,14-tri­aza­dibenz[a,j]anthracene 1,1,2,2-tetra­chloro­ethane monosolvate

The asymmetric unit of the title compound, C(19)H(11)N(3)·C(2)H(2)Cl(4), consists of one half-mol­ecule of 1,13,14-tri­aza­dibenz[a,j]anthracene (dibenzo[c,h]-1.9,10-anthyridine, dbanth) and one half of 1,1,2,2-tetra­chloro­ethane (TCE), both of which are located on a crystallographic twofold rotati...

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Detalles Bibliográficos
Autores principales: Koizumi, Take-aki, Hariu, Tomohiro, Sei, Yoshihisa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459339/
https://www.ncbi.nlm.nih.gov/pubmed/26090149
http://dx.doi.org/10.1107/S2056989015009263
Descripción
Sumario:The asymmetric unit of the title compound, C(19)H(11)N(3)·C(2)H(2)Cl(4), consists of one half-mol­ecule of 1,13,14-tri­aza­dibenz[a,j]anthracene (dibenzo[c,h]-1.9,10-anthyridine, dbanth) and one half of 1,1,2,2-tetra­chloro­ethane (TCE), both of which are located on a crystallographic twofold rotation axis. The dihedral angle between the planes of the terminal benzene rings in dbanth is 3.59 (7)° owing to the steric repulsion between the H atoms in the two benzo groups and the H atom in the central pyridine ring of the anthridine skeleton. In the crystal, π–π inter­actions between pyridine rings [centroid–centroid distances = 3.568 (2) and 3.594 (2) Å] link the dbanth mol­ecules to form a one-dimensional columnar structure along the c axis. The dbanth and TCE mol­ecules are connected through weak bifurcated C—H⋯(N,N) hydrogen bonds.