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Crystal structure of 1,13,14-triazadibenz[a,j]anthracene 1,1,2,2-tetrachloroethane monosolvate
The asymmetric unit of the title compound, C(19)H(11)N(3)·C(2)H(2)Cl(4), consists of one half-molecule of 1,13,14-triazadibenz[a,j]anthracene (dibenzo[c,h]-1.9,10-anthyridine, dbanth) and one half of 1,1,2,2-tetrachloroethane (TCE), both of which are located on a crystallographic twofold rotati...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459339/ https://www.ncbi.nlm.nih.gov/pubmed/26090149 http://dx.doi.org/10.1107/S2056989015009263 |
Sumario: | The asymmetric unit of the title compound, C(19)H(11)N(3)·C(2)H(2)Cl(4), consists of one half-molecule of 1,13,14-triazadibenz[a,j]anthracene (dibenzo[c,h]-1.9,10-anthyridine, dbanth) and one half of 1,1,2,2-tetrachloroethane (TCE), both of which are located on a crystallographic twofold rotation axis. The dihedral angle between the planes of the terminal benzene rings in dbanth is 3.59 (7)° owing to the steric repulsion between the H atoms in the two benzo groups and the H atom in the central pyridine ring of the anthridine skeleton. In the crystal, π–π interactions between pyridine rings [centroid–centroid distances = 3.568 (2) and 3.594 (2) Å] link the dbanth molecules to form a one-dimensional columnar structure along the c axis. The dbanth and TCE molecules are connected through weak bifurcated C—H⋯(N,N) hydrogen bonds. |
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