Cargando…

Crystal structure of 1,13,14-tri­aza­dibenz[a,j]anthracene 1,1,2,2-tetra­chloro­ethane monosolvate

The asymmetric unit of the title compound, C(19)H(11)N(3)·C(2)H(2)Cl(4), consists of one half-mol­ecule of 1,13,14-tri­aza­dibenz[a,j]anthracene (dibenzo[c,h]-1.9,10-anthyridine, dbanth) and one half of 1,1,2,2-tetra­chloro­ethane (TCE), both of which are located on a crystallographic twofold rotati...

Descripción completa

Detalles Bibliográficos
Autores principales: Koizumi, Take-aki, Hariu, Tomohiro, Sei, Yoshihisa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459339/
https://www.ncbi.nlm.nih.gov/pubmed/26090149
http://dx.doi.org/10.1107/S2056989015009263
_version_ 1782375207329071104
author Koizumi, Take-aki
Hariu, Tomohiro
Sei, Yoshihisa
author_facet Koizumi, Take-aki
Hariu, Tomohiro
Sei, Yoshihisa
author_sort Koizumi, Take-aki
collection PubMed
description The asymmetric unit of the title compound, C(19)H(11)N(3)·C(2)H(2)Cl(4), consists of one half-mol­ecule of 1,13,14-tri­aza­dibenz[a,j]anthracene (dibenzo[c,h]-1.9,10-anthyridine, dbanth) and one half of 1,1,2,2-tetra­chloro­ethane (TCE), both of which are located on a crystallographic twofold rotation axis. The dihedral angle between the planes of the terminal benzene rings in dbanth is 3.59 (7)° owing to the steric repulsion between the H atoms in the two benzo groups and the H atom in the central pyridine ring of the anthridine skeleton. In the crystal, π–π inter­actions between pyridine rings [centroid–centroid distances = 3.568 (2) and 3.594 (2) Å] link the dbanth mol­ecules to form a one-dimensional columnar structure along the c axis. The dbanth and TCE mol­ecules are connected through weak bifurcated C—H⋯(N,N) hydrogen bonds.
format Online
Article
Text
id pubmed-4459339
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-44593392015-06-18 Crystal structure of 1,13,14-tri­aza­dibenz[a,j]anthracene 1,1,2,2-tetra­chloro­ethane monosolvate Koizumi, Take-aki Hariu, Tomohiro Sei, Yoshihisa Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title compound, C(19)H(11)N(3)·C(2)H(2)Cl(4), consists of one half-mol­ecule of 1,13,14-tri­aza­dibenz[a,j]anthracene (dibenzo[c,h]-1.9,10-anthyridine, dbanth) and one half of 1,1,2,2-tetra­chloro­ethane (TCE), both of which are located on a crystallographic twofold rotation axis. The dihedral angle between the planes of the terminal benzene rings in dbanth is 3.59 (7)° owing to the steric repulsion between the H atoms in the two benzo groups and the H atom in the central pyridine ring of the anthridine skeleton. In the crystal, π–π inter­actions between pyridine rings [centroid–centroid distances = 3.568 (2) and 3.594 (2) Å] link the dbanth mol­ecules to form a one-dimensional columnar structure along the c axis. The dbanth and TCE mol­ecules are connected through weak bifurcated C—H⋯(N,N) hydrogen bonds. International Union of Crystallography 2015-05-23 /pmc/articles/PMC4459339/ /pubmed/26090149 http://dx.doi.org/10.1107/S2056989015009263 Text en © Koizumi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Koizumi, Take-aki
Hariu, Tomohiro
Sei, Yoshihisa
Crystal structure of 1,13,14-tri­aza­dibenz[a,j]anthracene 1,1,2,2-tetra­chloro­ethane monosolvate
title Crystal structure of 1,13,14-tri­aza­dibenz[a,j]anthracene 1,1,2,2-tetra­chloro­ethane monosolvate
title_full Crystal structure of 1,13,14-tri­aza­dibenz[a,j]anthracene 1,1,2,2-tetra­chloro­ethane monosolvate
title_fullStr Crystal structure of 1,13,14-tri­aza­dibenz[a,j]anthracene 1,1,2,2-tetra­chloro­ethane monosolvate
title_full_unstemmed Crystal structure of 1,13,14-tri­aza­dibenz[a,j]anthracene 1,1,2,2-tetra­chloro­ethane monosolvate
title_short Crystal structure of 1,13,14-tri­aza­dibenz[a,j]anthracene 1,1,2,2-tetra­chloro­ethane monosolvate
title_sort crystal structure of 1,13,14-tri­aza­dibenz[a,j]anthracene 1,1,2,2-tetra­chloro­ethane monosolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459339/
https://www.ncbi.nlm.nih.gov/pubmed/26090149
http://dx.doi.org/10.1107/S2056989015009263
work_keys_str_mv AT koizumitakeaki crystalstructureof11314triazadibenzajanthracene1122tetrachloroethanemonosolvate
AT hariutomohiro crystalstructureof11314triazadibenzajanthracene1122tetrachloroethanemonosolvate
AT seiyoshihisa crystalstructureof11314triazadibenzajanthracene1122tetrachloroethanemonosolvate