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Crystal structure of dibenzyldimethylsilane
In the title compound, C(16)H(20)Si, a geometry different from an ideal tetrahedron can be observed at the Si atom. The bonds from Si to the benzylic C atoms [Si—C = 1.884 (1) and 1.883 (1) Å] are slightly elongated compared to the Si—C(methyl) bonds [Si—C = 1.856 (1) and 1.853 (1) Å]. The C(benz...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459354/ https://www.ncbi.nlm.nih.gov/pubmed/26090183 http://dx.doi.org/10.1107/S2056989015008713 |
Sumario: | In the title compound, C(16)H(20)Si, a geometry different from an ideal tetrahedron can be observed at the Si atom. The bonds from Si to the benzylic C atoms [Si—C = 1.884 (1) and 1.883 (1) Å] are slightly elongated compared to the Si—C(methyl) bonds [Si—C = 1.856 (1) and 1.853 (1) Å]. The C(benzyl)—Si—C(benzyl) bond angle [C—Si—C = 107.60 (6)°] is decreased from the ideal tetrahedral angle by 1.9°. These distortions can be explained easily by Bent’s rule. In the crystal, molecules interact only by van der Waals forces. |
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