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Crystal structure of di­benzyl­dimethyl­silane

In the title compound, C(16)H(20)Si, a geometry different from an ideal tetra­hedron can be observed at the Si atom. The bonds from Si to the benzylic C atoms [Si—C = 1.884 (1) and 1.883 (1) Å] are slightly elongated compared to the Si—C(meth­yl) bonds [Si—C = 1.856 (1) and 1.853 (1) Å]. The C(benz­...

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Autores principales: Knauer, Lena, Golz, Christopher, Kroesen, Ulrike, Koller, Stephan G., Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459354/
https://www.ncbi.nlm.nih.gov/pubmed/26090183
http://dx.doi.org/10.1107/S2056989015008713
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author Knauer, Lena
Golz, Christopher
Kroesen, Ulrike
Koller, Stephan G.
Strohmann, Carsten
author_facet Knauer, Lena
Golz, Christopher
Kroesen, Ulrike
Koller, Stephan G.
Strohmann, Carsten
author_sort Knauer, Lena
collection PubMed
description In the title compound, C(16)H(20)Si, a geometry different from an ideal tetra­hedron can be observed at the Si atom. The bonds from Si to the benzylic C atoms [Si—C = 1.884 (1) and 1.883 (1) Å] are slightly elongated compared to the Si—C(meth­yl) bonds [Si—C = 1.856 (1) and 1.853 (1) Å]. The C(benz­yl)—Si—C(benz­yl) bond angle [C—Si—C = 107.60 (6)°] is decreased from the ideal tetra­hedral angle by 1.9°. These distortions can be explained easily by Bent’s rule. In the crystal, mol­ecules inter­act only by van der Waals forces.
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spelling pubmed-44593542015-06-18 Crystal structure of di­benzyl­dimethyl­silane Knauer, Lena Golz, Christopher Kroesen, Ulrike Koller, Stephan G. Strohmann, Carsten Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(16)H(20)Si, a geometry different from an ideal tetra­hedron can be observed at the Si atom. The bonds from Si to the benzylic C atoms [Si—C = 1.884 (1) and 1.883 (1) Å] are slightly elongated compared to the Si—C(meth­yl) bonds [Si—C = 1.856 (1) and 1.853 (1) Å]. The C(benz­yl)—Si—C(benz­yl) bond angle [C—Si—C = 107.60 (6)°] is decreased from the ideal tetra­hedral angle by 1.9°. These distortions can be explained easily by Bent’s rule. In the crystal, mol­ecules inter­act only by van der Waals forces. International Union of Crystallography 2015-05-09 /pmc/articles/PMC4459354/ /pubmed/26090183 http://dx.doi.org/10.1107/S2056989015008713 Text en © Knauer et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Knauer, Lena
Golz, Christopher
Kroesen, Ulrike
Koller, Stephan G.
Strohmann, Carsten
Crystal structure of di­benzyl­dimethyl­silane
title Crystal structure of di­benzyl­dimethyl­silane
title_full Crystal structure of di­benzyl­dimethyl­silane
title_fullStr Crystal structure of di­benzyl­dimethyl­silane
title_full_unstemmed Crystal structure of di­benzyl­dimethyl­silane
title_short Crystal structure of di­benzyl­dimethyl­silane
title_sort crystal structure of di­benzyl­dimethyl­silane
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459354/
https://www.ncbi.nlm.nih.gov/pubmed/26090183
http://dx.doi.org/10.1107/S2056989015008713
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