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Crystal structure of dibenzyldimethylsilane
In the title compound, C(16)H(20)Si, a geometry different from an ideal tetrahedron can be observed at the Si atom. The bonds from Si to the benzylic C atoms [Si—C = 1.884 (1) and 1.883 (1) Å] are slightly elongated compared to the Si—C(methyl) bonds [Si—C = 1.856 (1) and 1.853 (1) Å]. The C(benz...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459354/ https://www.ncbi.nlm.nih.gov/pubmed/26090183 http://dx.doi.org/10.1107/S2056989015008713 |
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author | Knauer, Lena Golz, Christopher Kroesen, Ulrike Koller, Stephan G. Strohmann, Carsten |
author_facet | Knauer, Lena Golz, Christopher Kroesen, Ulrike Koller, Stephan G. Strohmann, Carsten |
author_sort | Knauer, Lena |
collection | PubMed |
description | In the title compound, C(16)H(20)Si, a geometry different from an ideal tetrahedron can be observed at the Si atom. The bonds from Si to the benzylic C atoms [Si—C = 1.884 (1) and 1.883 (1) Å] are slightly elongated compared to the Si—C(methyl) bonds [Si—C = 1.856 (1) and 1.853 (1) Å]. The C(benzyl)—Si—C(benzyl) bond angle [C—Si—C = 107.60 (6)°] is decreased from the ideal tetrahedral angle by 1.9°. These distortions can be explained easily by Bent’s rule. In the crystal, molecules interact only by van der Waals forces. |
format | Online Article Text |
id | pubmed-4459354 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44593542015-06-18 Crystal structure of dibenzyldimethylsilane Knauer, Lena Golz, Christopher Kroesen, Ulrike Koller, Stephan G. Strohmann, Carsten Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(16)H(20)Si, a geometry different from an ideal tetrahedron can be observed at the Si atom. The bonds from Si to the benzylic C atoms [Si—C = 1.884 (1) and 1.883 (1) Å] are slightly elongated compared to the Si—C(methyl) bonds [Si—C = 1.856 (1) and 1.853 (1) Å]. The C(benzyl)—Si—C(benzyl) bond angle [C—Si—C = 107.60 (6)°] is decreased from the ideal tetrahedral angle by 1.9°. These distortions can be explained easily by Bent’s rule. In the crystal, molecules interact only by van der Waals forces. International Union of Crystallography 2015-05-09 /pmc/articles/PMC4459354/ /pubmed/26090183 http://dx.doi.org/10.1107/S2056989015008713 Text en © Knauer et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Knauer, Lena Golz, Christopher Kroesen, Ulrike Koller, Stephan G. Strohmann, Carsten Crystal structure of dibenzyldimethylsilane |
title | Crystal structure of dibenzyldimethylsilane |
title_full | Crystal structure of dibenzyldimethylsilane |
title_fullStr | Crystal structure of dibenzyldimethylsilane |
title_full_unstemmed | Crystal structure of dibenzyldimethylsilane |
title_short | Crystal structure of dibenzyldimethylsilane |
title_sort | crystal structure of dibenzyldimethylsilane |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459354/ https://www.ncbi.nlm.nih.gov/pubmed/26090183 http://dx.doi.org/10.1107/S2056989015008713 |
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