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Crystal structure of 14-methyl-11-(3-methylphenyl)-12-oxa-8,14-diazatetracyclo[8.3.3.0(1,10).0(2,7)]hexadeca-2(7),3,5-triene-9,13-dione
In the title compound, C(21)H(20)N(2)O(3), the lactone ring adopts an envelope conformation with the quaternary C atom bonded to two other C atoms as the flap. The fused pyrrolidine ring adopts a twisted conformation about the C(q)—N (q = quaternary) bond. In the crystal, inversion dimers linked by...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459358/ https://www.ncbi.nlm.nih.gov/pubmed/26090176 http://dx.doi.org/10.1107/S2056989015008129 |
| _version_ | 1782375211911348224 |
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| author | Savithri, M. P. Suresh, M. Raghunathan, R. Raja, R. SubbiahPandi, A. |
| author_facet | Savithri, M. P. Suresh, M. Raghunathan, R. Raja, R. SubbiahPandi, A. |
| author_sort | Savithri, M. P. |
| collection | PubMed |
| description | In the title compound, C(21)H(20)N(2)O(3), the lactone ring adopts an envelope conformation with the quaternary C atom bonded to two other C atoms as the flap. The fused pyrrolidine ring adopts a twisted conformation about the C(q)—N (q = quaternary) bond. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. The dimers are linked into [110] chains by pairs of C—H⋯O interactions, which generate R (2) (2)(14) loops. |
| format | Online Article Text |
| id | pubmed-4459358 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2015 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-44593582015-06-18 Crystal structure of 14-methyl-11-(3-methylphenyl)-12-oxa-8,14-diazatetracyclo[8.3.3.0(1,10).0(2,7)]hexadeca-2(7),3,5-triene-9,13-dione Savithri, M. P. Suresh, M. Raghunathan, R. Raja, R. SubbiahPandi, A. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(21)H(20)N(2)O(3), the lactone ring adopts an envelope conformation with the quaternary C atom bonded to two other C atoms as the flap. The fused pyrrolidine ring adopts a twisted conformation about the C(q)—N (q = quaternary) bond. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. The dimers are linked into [110] chains by pairs of C—H⋯O interactions, which generate R (2) (2)(14) loops. International Union of Crystallography 2015-05-07 /pmc/articles/PMC4459358/ /pubmed/26090176 http://dx.doi.org/10.1107/S2056989015008129 Text en © Savithri et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Savithri, M. P. Suresh, M. Raghunathan, R. Raja, R. SubbiahPandi, A. Crystal structure of 14-methyl-11-(3-methylphenyl)-12-oxa-8,14-diazatetracyclo[8.3.3.0(1,10).0(2,7)]hexadeca-2(7),3,5-triene-9,13-dione |
| title | Crystal structure of 14-methyl-11-(3-methylphenyl)-12-oxa-8,14-diazatetracyclo[8.3.3.0(1,10).0(2,7)]hexadeca-2(7),3,5-triene-9,13-dione |
| title_full | Crystal structure of 14-methyl-11-(3-methylphenyl)-12-oxa-8,14-diazatetracyclo[8.3.3.0(1,10).0(2,7)]hexadeca-2(7),3,5-triene-9,13-dione |
| title_fullStr | Crystal structure of 14-methyl-11-(3-methylphenyl)-12-oxa-8,14-diazatetracyclo[8.3.3.0(1,10).0(2,7)]hexadeca-2(7),3,5-triene-9,13-dione |
| title_full_unstemmed | Crystal structure of 14-methyl-11-(3-methylphenyl)-12-oxa-8,14-diazatetracyclo[8.3.3.0(1,10).0(2,7)]hexadeca-2(7),3,5-triene-9,13-dione |
| title_short | Crystal structure of 14-methyl-11-(3-methylphenyl)-12-oxa-8,14-diazatetracyclo[8.3.3.0(1,10).0(2,7)]hexadeca-2(7),3,5-triene-9,13-dione |
| title_sort | crystal structure of 14-methyl-11-(3-methylphenyl)-12-oxa-8,14-diazatetracyclo[8.3.3.0(1,10).0(2,7)]hexadeca-2(7),3,5-triene-9,13-dione |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459358/ https://www.ncbi.nlm.nih.gov/pubmed/26090176 http://dx.doi.org/10.1107/S2056989015008129 |
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