Crystal structure of methyl (2Z)-3-(4-chloro­phen­yl)-2-[(3-methyl-1H-indol-1-yl)meth­yl]prop-2-enoate

In the title indole derivative, C(20)H(18)ClNO(2), the chloro­phenyl ring is almost perpendicular to the indole moiety, making a dihedral angle of 87.6 (1)°. The mol­ecular packing is stabilized by C—H⋯π inter­actions, which form a C(9) chain motif along [10-1]. In addition, there are weak π–π inter...

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Autores principales: Selvanayagam, S., Sridhar, B., Kathiravan, S., Raghunathan, R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459359/
https://www.ncbi.nlm.nih.gov/pubmed/26090160
http://dx.doi.org/10.1107/S2056989015010002
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author Selvanayagam, S.
Sridhar, B.
Kathiravan, S.
Raghunathan, R.
author_facet Selvanayagam, S.
Sridhar, B.
Kathiravan, S.
Raghunathan, R.
author_sort Selvanayagam, S.
collection PubMed
description In the title indole derivative, C(20)H(18)ClNO(2), the chloro­phenyl ring is almost perpendicular to the indole moiety, making a dihedral angle of 87.6 (1)°. The mol­ecular packing is stabilized by C—H⋯π inter­actions, which form a C(9) chain motif along [10-1]. In addition, there are weak π–π inter­actions [centroid–centroid distance 3.851 (1) Å] between the chains, involving inversion-related chloro­phenyl rings.
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spelling pubmed-44593592015-06-18 Crystal structure of methyl (2Z)-3-(4-chloro­phen­yl)-2-[(3-methyl-1H-indol-1-yl)meth­yl]prop-2-enoate Selvanayagam, S. Sridhar, B. Kathiravan, S. Raghunathan, R. Acta Crystallogr E Crystallogr Commun Research Communications In the title indole derivative, C(20)H(18)ClNO(2), the chloro­phenyl ring is almost perpendicular to the indole moiety, making a dihedral angle of 87.6 (1)°. The mol­ecular packing is stabilized by C—H⋯π inter­actions, which form a C(9) chain motif along [10-1]. In addition, there are weak π–π inter­actions [centroid–centroid distance 3.851 (1) Å] between the chains, involving inversion-related chloro­phenyl rings. International Union of Crystallography 2015-05-30 /pmc/articles/PMC4459359/ /pubmed/26090160 http://dx.doi.org/10.1107/S2056989015010002 Text en © Selvanayagam et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Selvanayagam, S.
Sridhar, B.
Kathiravan, S.
Raghunathan, R.
Crystal structure of methyl (2Z)-3-(4-chloro­phen­yl)-2-[(3-methyl-1H-indol-1-yl)meth­yl]prop-2-enoate
title Crystal structure of methyl (2Z)-3-(4-chloro­phen­yl)-2-[(3-methyl-1H-indol-1-yl)meth­yl]prop-2-enoate
title_full Crystal structure of methyl (2Z)-3-(4-chloro­phen­yl)-2-[(3-methyl-1H-indol-1-yl)meth­yl]prop-2-enoate
title_fullStr Crystal structure of methyl (2Z)-3-(4-chloro­phen­yl)-2-[(3-methyl-1H-indol-1-yl)meth­yl]prop-2-enoate
title_full_unstemmed Crystal structure of methyl (2Z)-3-(4-chloro­phen­yl)-2-[(3-methyl-1H-indol-1-yl)meth­yl]prop-2-enoate
title_short Crystal structure of methyl (2Z)-3-(4-chloro­phen­yl)-2-[(3-methyl-1H-indol-1-yl)meth­yl]prop-2-enoate
title_sort crystal structure of methyl (2z)-3-(4-chloro­phen­yl)-2-[(3-methyl-1h-indol-1-yl)meth­yl]prop-2-enoate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459359/
https://www.ncbi.nlm.nih.gov/pubmed/26090160
http://dx.doi.org/10.1107/S2056989015010002
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