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Crystal structure of 2,2-dimethyl-N-(5-methyl­pyridin-2-yl)propanamide

There are two mol­ecules in the asymmetric unit of the title compound, C(11)H(16)N(2)O. The pyridine rings and amide groups overlap almost perfectly (r.m.s. overlay fit = 0.053 Å), but the tertiary butyl groups have different orientations: in one mol­ecule, one of the methyl C atoms is syn to the am...

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Autores principales: El-Hiti, Gamal A., Smith, Keith, Hegazy, Amany S., Alanazi, Saud A., Kariuki, Benson M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459364/
https://www.ncbi.nlm.nih.gov/pubmed/26090202
http://dx.doi.org/10.1107/S2056989015009378
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author El-Hiti, Gamal A.
Smith, Keith
Hegazy, Amany S.
Alanazi, Saud A.
Kariuki, Benson M.
author_facet El-Hiti, Gamal A.
Smith, Keith
Hegazy, Amany S.
Alanazi, Saud A.
Kariuki, Benson M.
author_sort El-Hiti, Gamal A.
collection PubMed
description There are two mol­ecules in the asymmetric unit of the title compound, C(11)H(16)N(2)O. The pyridine rings and amide groups overlap almost perfectly (r.m.s. overlay fit = 0.053 Å), but the tertiary butyl groups have different orientations: in one mol­ecule, one of the methyl C atoms is syn to the amide O atom [O—C—C—C = −0.8 (3)°] and in the other the equivalent torsion angle is 31.0 (2)°. In the crystal, the two independent mol­ecules are linked by a pair of N—H⋯N hydrogen bonds in the form of an R (2) (2)(8) loop to form a dimer. A C—H⋯O inter­action connects the dimers into [100] chains.
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spelling pubmed-44593642015-06-18 Crystal structure of 2,2-dimethyl-N-(5-methyl­pyridin-2-yl)propanamide El-Hiti, Gamal A. Smith, Keith Hegazy, Amany S. Alanazi, Saud A. Kariuki, Benson M. Acta Crystallogr E Crystallogr Commun Data Reports There are two mol­ecules in the asymmetric unit of the title compound, C(11)H(16)N(2)O. The pyridine rings and amide groups overlap almost perfectly (r.m.s. overlay fit = 0.053 Å), but the tertiary butyl groups have different orientations: in one mol­ecule, one of the methyl C atoms is syn to the amide O atom [O—C—C—C = −0.8 (3)°] and in the other the equivalent torsion angle is 31.0 (2)°. In the crystal, the two independent mol­ecules are linked by a pair of N—H⋯N hydrogen bonds in the form of an R (2) (2)(8) loop to form a dimer. A C—H⋯O inter­action connects the dimers into [100] chains. International Union of Crystallography 2015-05-23 /pmc/articles/PMC4459364/ /pubmed/26090202 http://dx.doi.org/10.1107/S2056989015009378 Text en © El-Hiti et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
El-Hiti, Gamal A.
Smith, Keith
Hegazy, Amany S.
Alanazi, Saud A.
Kariuki, Benson M.
Crystal structure of 2,2-dimethyl-N-(5-methyl­pyridin-2-yl)propanamide
title Crystal structure of 2,2-dimethyl-N-(5-methyl­pyridin-2-yl)propanamide
title_full Crystal structure of 2,2-dimethyl-N-(5-methyl­pyridin-2-yl)propanamide
title_fullStr Crystal structure of 2,2-dimethyl-N-(5-methyl­pyridin-2-yl)propanamide
title_full_unstemmed Crystal structure of 2,2-dimethyl-N-(5-methyl­pyridin-2-yl)propanamide
title_short Crystal structure of 2,2-dimethyl-N-(5-methyl­pyridin-2-yl)propanamide
title_sort crystal structure of 2,2-dimethyl-n-(5-methyl­pyridin-2-yl)propanamide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459364/
https://www.ncbi.nlm.nih.gov/pubmed/26090202
http://dx.doi.org/10.1107/S2056989015009378
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