Crystal structure of trans-di­chlorido­(4-nitro­aniline-κN (1))(piperidine-κN)platinum(II)

In the title complex, [PtCl(2)(C(5)H(11)N)(C(6)H(6)N(2)O(2))], the Pt(II) metal atom displays a slightly distorted trans-PtN(2)Cl(2) square-planar coordination geometry. The dihedral angle between the mean plane of the benzene and piperidine rings is 89.03 (3)°. In the crystal structure, inversion d...

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Detalles Bibliográficos
Autores principales: Nguyen Thi Thanh, Chi, Hoang Van, Truong, Pham Van, Thong, Nguyen Bich, Ngan, Van Meervelt, Luc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459372/
https://www.ncbi.nlm.nih.gov/pubmed/26090140
http://dx.doi.org/10.1107/S2056989015009196
Descripción
Sumario:In the title complex, [PtCl(2)(C(5)H(11)N)(C(6)H(6)N(2)O(2))], the Pt(II) metal atom displays a slightly distorted trans-PtN(2)Cl(2) square-planar coordination geometry. The dihedral angle between the mean plane of the benzene and piperidine rings is 89.03 (3)°. In the crystal structure, inversion dimers are formed via N—H⋯Cl hydrogen-bond inter­actions, resulting in chains parallel to the [001] direction. The benzene rings within the chains show π–π stacking inter­actions [centroid-to-centroid distances of 3.801 (3) Å] and neighbouring chains inter­act via N—H⋯O hydrogen bonds.

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