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Crystal structure of trans-dichlorido(4-nitroaniline-κN (1))(piperidine-κN)platinum(II)
In the title complex, [PtCl(2)(C(5)H(11)N)(C(6)H(6)N(2)O(2))], the Pt(II) metal atom displays a slightly distorted trans-PtN(2)Cl(2) square-planar coordination geometry. The dihedral angle between the mean plane of the benzene and piperidine rings is 89.03 (3)°. In the crystal structure, inversion d...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459372/ https://www.ncbi.nlm.nih.gov/pubmed/26090140 http://dx.doi.org/10.1107/S2056989015009196 |
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| author | Nguyen Thi Thanh, Chi Hoang Van, Truong Pham Van, Thong Nguyen Bich, Ngan Van Meervelt, Luc |
| author_facet | Nguyen Thi Thanh, Chi Hoang Van, Truong Pham Van, Thong Nguyen Bich, Ngan Van Meervelt, Luc |
| author_sort | Nguyen Thi Thanh, Chi |
| collection | PubMed |
| description | In the title complex, [PtCl(2)(C(5)H(11)N)(C(6)H(6)N(2)O(2))], the Pt(II) metal atom displays a slightly distorted trans-PtN(2)Cl(2) square-planar coordination geometry. The dihedral angle between the mean plane of the benzene and piperidine rings is 89.03 (3)°. In the crystal structure, inversion dimers are formed via N—H⋯Cl hydrogen-bond interactions, resulting in chains parallel to the [001] direction. The benzene rings within the chains show π–π stacking interactions [centroid-to-centroid distances of 3.801 (3) Å] and neighbouring chains interact via N—H⋯O hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-4459372 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2015 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-44593722015-06-18 Crystal structure of trans-dichlorido(4-nitroaniline-κN (1))(piperidine-κN)platinum(II) Nguyen Thi Thanh, Chi Hoang Van, Truong Pham Van, Thong Nguyen Bich, Ngan Van Meervelt, Luc Acta Crystallogr E Crystallogr Commun Research Communications In the title complex, [PtCl(2)(C(5)H(11)N)(C(6)H(6)N(2)O(2))], the Pt(II) metal atom displays a slightly distorted trans-PtN(2)Cl(2) square-planar coordination geometry. The dihedral angle between the mean plane of the benzene and piperidine rings is 89.03 (3)°. In the crystal structure, inversion dimers are formed via N—H⋯Cl hydrogen-bond interactions, resulting in chains parallel to the [001] direction. The benzene rings within the chains show π–π stacking interactions [centroid-to-centroid distances of 3.801 (3) Å] and neighbouring chains interact via N—H⋯O hydrogen bonds. International Union of Crystallography 2015-05-20 /pmc/articles/PMC4459372/ /pubmed/26090140 http://dx.doi.org/10.1107/S2056989015009196 Text en © Nguyen Thi Thanh et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Nguyen Thi Thanh, Chi Hoang Van, Truong Pham Van, Thong Nguyen Bich, Ngan Van Meervelt, Luc Crystal structure of trans-dichlorido(4-nitroaniline-κN (1))(piperidine-κN)platinum(II) |
| title | Crystal structure of trans-dichlorido(4-nitroaniline-κN
(1))(piperidine-κN)platinum(II) |
| title_full | Crystal structure of trans-dichlorido(4-nitroaniline-κN
(1))(piperidine-κN)platinum(II) |
| title_fullStr | Crystal structure of trans-dichlorido(4-nitroaniline-κN
(1))(piperidine-κN)platinum(II) |
| title_full_unstemmed | Crystal structure of trans-dichlorido(4-nitroaniline-κN
(1))(piperidine-κN)platinum(II) |
| title_short | Crystal structure of trans-dichlorido(4-nitroaniline-κN
(1))(piperidine-κN)platinum(II) |
| title_sort | crystal structure of trans-dichlorido(4-nitroaniline-κn
(1))(piperidine-κn)platinum(ii) |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459372/ https://www.ncbi.nlm.nih.gov/pubmed/26090140 http://dx.doi.org/10.1107/S2056989015009196 |
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