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Crystal structure of an unknown solvate of bis­(tetra-n-butyl­ammonium) [N,N′-(4-tri­fluoro­methyl-1,2-phenyl­ene)bis­(oxamato)-κ(4) O,N,N′,O′]nickelate(II)

In the title compound, [N(C(4)H(9))(4)](2)[Ni(C(11)H(3)F(3)N(2)O(6))] or [N(n-Bu)(4)](2)[Ni(topbo)] [n-Bu = n-butyl and topbo = 4-tri­fluoro­methyl-1,2-phenyl­enebis(oxamate)], the Ni(2+) cation is coordinated by two deprotonated amido N atoms and two carboxyl­ate O atoms, setting up a slightly dist...

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Detalles Bibliográficos
Autores principales: Eya’ane Meva, François, Schaarschmidt, Dieter, Rüffer, Tobias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459374/
https://www.ncbi.nlm.nih.gov/pubmed/26090126
http://dx.doi.org/10.1107/S205698901500835X
Descripción
Sumario:In the title compound, [N(C(4)H(9))(4)](2)[Ni(C(11)H(3)F(3)N(2)O(6))] or [N(n-Bu)(4)](2)[Ni(topbo)] [n-Bu = n-butyl and topbo = 4-tri­fluoro­methyl-1,2-phenyl­enebis(oxamate)], the Ni(2+) cation is coordinated by two deprotonated amido N atoms and two carboxyl­ate O atoms, setting up a slightly distorted square-planar coordination environment. The [Ni(topbo](2−) anion lies on a twofold rotation axis. Due to an incompatibility with the point-group symmetry of the complete mol­ecule, orientational disorder of the CF(3) group is observed. The tetra­hedral ammonium cations and the anion are linked by weak inter­molecular C—H⋯O and C—H⋯F hydrogen-bonding inter­actions into a three-dimensional network. A region of electron density was treated with the SQUEEZE procedure in PLATON [Spek (2015). Acta Cryst. C71, 9–18] following unsuccessful attempts to model it as plausible solvent mol­ecule(s). The given chemical formula and other crystal data do not take into account the unknown solvent mol­ecule.