Crystal structure of aqua­[(E)-N′-(5-bromo-2-oxido­benzyl­idene-κO)benzohydrazidato-κ(2) O,N′]dioxidomolybdenum(VI) di­methyl­formamide monosolvate

The title compound, [Mo(C(14)H(9)BrN(2)O(2))O(2)(H(2)O)]·C(3)H(7)NO, has a distorted octa­hedral geometry around the Mo atom, with the two terminal oxide groups lying cis to each other. The two aromatic rings present in the mol­ecule are almost coplanar, forming a dihedral angle of 1.4 (2)°. The five-membered ring involving the metal atom is puckered, with an amplitude Q = 0.358 (2) Å and ϕ = 204.1 (6)°. In the crystal, pairs of inversion-related mol­ecules are linked by O—H⋯N hydrogen bonds. An O—H⋯O hydrogen bond connects the water ligand to the di­methyl­formamide solvent mol­ecule. The crystal packing also features π–π [centroid–centroid distance of 3.688 (2) Å] and C—H⋯O inter­actions.