Crystal structure of aqua­[(E)-N′-(5-bromo-2-oxido­benzyl­idene-κO)benzohydrazidato-κ(2) O,N′]dioxidomolybdenum(VI) di­methyl­formamide monosolvate

The title compound, [Mo(C(14)H(9)BrN(2)O(2))O(2)(H(2)O)]·C(3)H(7)NO, has a distorted octa­hedral geometry around the Mo atom, with the two terminal oxide groups lying cis to each other. The two aromatic rings present in the mol­ecule are almost coplanar, forming a dihedral angle of 1.4 (2)°. The fiv...

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Autores principales: Sudheer, Radhika, Sithambaresan, M., Sajitha, N. R., Manoj, E., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459377/
https://www.ncbi.nlm.nih.gov/pubmed/26090155
http://dx.doi.org/10.1107/S2056989015009639
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author Sudheer, Radhika
Sithambaresan, M.
Sajitha, N. R.
Manoj, E.
Kurup, M. R. Prathapachandra
author_facet Sudheer, Radhika
Sithambaresan, M.
Sajitha, N. R.
Manoj, E.
Kurup, M. R. Prathapachandra
author_sort Sudheer, Radhika
collection PubMed
description The title compound, [Mo(C(14)H(9)BrN(2)O(2))O(2)(H(2)O)]·C(3)H(7)NO, has a distorted octa­hedral geometry around the Mo atom, with the two terminal oxide groups lying cis to each other. The two aromatic rings present in the mol­ecule are almost coplanar, forming a dihedral angle of 1.4 (2)°. The five-membered ring involving the metal atom is puckered, with an amplitude Q = 0.358 (2) Å and ϕ = 204.1 (6)°. In the crystal, pairs of inversion-related mol­ecules are linked by O—H⋯N hydrogen bonds. An O—H⋯O hydrogen bond connects the water ligand to the di­methyl­formamide solvent mol­ecule. The crystal packing also features π–π [centroid–centroid distance of 3.688 (2) Å] and C—H⋯O inter­actions.
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spelling pubmed-44593772015-06-18 Crystal structure of aqua­[(E)-N′-(5-bromo-2-oxido­benzyl­idene-κO)benzohydrazidato-κ(2) O,N′]dioxidomolybdenum(VI) di­methyl­formamide monosolvate Sudheer, Radhika Sithambaresan, M. Sajitha, N. R. Manoj, E. Kurup, M. R. Prathapachandra Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [Mo(C(14)H(9)BrN(2)O(2))O(2)(H(2)O)]·C(3)H(7)NO, has a distorted octa­hedral geometry around the Mo atom, with the two terminal oxide groups lying cis to each other. The two aromatic rings present in the mol­ecule are almost coplanar, forming a dihedral angle of 1.4 (2)°. The five-membered ring involving the metal atom is puckered, with an amplitude Q = 0.358 (2) Å and ϕ = 204.1 (6)°. In the crystal, pairs of inversion-related mol­ecules are linked by O—H⋯N hydrogen bonds. An O—H⋯O hydrogen bond connects the water ligand to the di­methyl­formamide solvent mol­ecule. The crystal packing also features π–π [centroid–centroid distance of 3.688 (2) Å] and C—H⋯O inter­actions. International Union of Crystallography 2015-05-28 /pmc/articles/PMC4459377/ /pubmed/26090155 http://dx.doi.org/10.1107/S2056989015009639 Text en © Sudheer et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Sudheer, Radhika
Sithambaresan, M.
Sajitha, N. R.
Manoj, E.
Kurup, M. R. Prathapachandra
Crystal structure of aqua­[(E)-N′-(5-bromo-2-oxido­benzyl­idene-κO)benzohydrazidato-κ(2) O,N′]dioxidomolybdenum(VI) di­methyl­formamide monosolvate
title Crystal structure of aqua­[(E)-N′-(5-bromo-2-oxido­benzyl­idene-κO)benzohydrazidato-κ(2) O,N′]dioxidomolybdenum(VI) di­methyl­formamide monosolvate
title_full Crystal structure of aqua­[(E)-N′-(5-bromo-2-oxido­benzyl­idene-κO)benzohydrazidato-κ(2) O,N′]dioxidomolybdenum(VI) di­methyl­formamide monosolvate
title_fullStr Crystal structure of aqua­[(E)-N′-(5-bromo-2-oxido­benzyl­idene-κO)benzohydrazidato-κ(2) O,N′]dioxidomolybdenum(VI) di­methyl­formamide monosolvate
title_full_unstemmed Crystal structure of aqua­[(E)-N′-(5-bromo-2-oxido­benzyl­idene-κO)benzohydrazidato-κ(2) O,N′]dioxidomolybdenum(VI) di­methyl­formamide monosolvate
title_short Crystal structure of aqua­[(E)-N′-(5-bromo-2-oxido­benzyl­idene-κO)benzohydrazidato-κ(2) O,N′]dioxidomolybdenum(VI) di­methyl­formamide monosolvate
title_sort crystal structure of aqua­[(e)-n′-(5-bromo-2-oxido­benzyl­idene-κo)benzohydrazidato-κ(2) o,n′]dioxidomolybdenum(vi) di­methyl­formamide monosolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459377/
https://www.ncbi.nlm.nih.gov/pubmed/26090155
http://dx.doi.org/10.1107/S2056989015009639
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