Crystal structure of poly[[μ-1,1′-(butane-1,4-di­yl)bis­(1H-benzimidazole)-κ(2) N (3):N (3′)]{μ-4,4′-[1,4-phenyl­enebis(­oxy)]di­ben­zo­ato-κ(4) O,O′:O′′,O′′′}cobalt(II)]

In the title compound, [Co(C(20)H(12)O(6))(C(18)H(18)N(4))](n), the Co(II) atom, located on a twofold rotation axis, is hexa­coordinated to four O from two bis-bidentate 4,4′-[phenyl­enebis(­oxy)]dibenzoate (L) ligands and two N atoms from two 1,1′-(butane-1,4-di­yl)bis­(1H-benzimidazole) (bbbm) lig...

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Detalles Bibliográficos
Autores principales: Xie, Chen, Zheng, ChangGe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459380/
https://www.ncbi.nlm.nih.gov/pubmed/26090167
http://dx.doi.org/10.1107/S2056989015008294
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author Xie, Chen
Zheng, ChangGe
author_facet Xie, Chen
Zheng, ChangGe
author_sort Xie, Chen
collection PubMed
description In the title compound, [Co(C(20)H(12)O(6))(C(18)H(18)N(4))](n), the Co(II) atom, located on a twofold rotation axis, is hexa­coordinated to four O from two bis-bidentate 4,4′-[phenyl­enebis(­oxy)]dibenzoate (L) ligands and two N atoms from two 1,1′-(butane-1,4-di­yl)bis­(1H-benzimidazole) (bbbm) ligands, forming a distorted octahedral cis-N(2)O(4) coordination environment. Polymeric zigzag chains along [102] are built up by the bridging L ligands. These chains are additionally connected by the bbbm ligands to produce a two-dimensional coordination polymer parallel too (010).
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spelling pubmed-44593802015-06-18 Crystal structure of poly[[μ-1,1′-(butane-1,4-di­yl)bis­(1H-benzimidazole)-κ(2) N (3):N (3′)]{μ-4,4′-[1,4-phenyl­enebis(­oxy)]di­ben­zo­ato-κ(4) O,O′:O′′,O′′′}cobalt(II)] Xie, Chen Zheng, ChangGe Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, [Co(C(20)H(12)O(6))(C(18)H(18)N(4))](n), the Co(II) atom, located on a twofold rotation axis, is hexa­coordinated to four O from two bis-bidentate 4,4′-[phenyl­enebis(­oxy)]dibenzoate (L) ligands and two N atoms from two 1,1′-(butane-1,4-di­yl)bis­(1H-benzimidazole) (bbbm) ligands, forming a distorted octahedral cis-N(2)O(4) coordination environment. Polymeric zigzag chains along [102] are built up by the bridging L ligands. These chains are additionally connected by the bbbm ligands to produce a two-dimensional coordination polymer parallel too (010). International Union of Crystallography 2015-05-20 /pmc/articles/PMC4459380/ /pubmed/26090167 http://dx.doi.org/10.1107/S2056989015008294 Text en © Xie and Zheng 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Xie, Chen
Zheng, ChangGe
Crystal structure of poly[[μ-1,1′-(butane-1,4-di­yl)bis­(1H-benzimidazole)-κ(2) N (3):N (3′)]{μ-4,4′-[1,4-phenyl­enebis(­oxy)]di­ben­zo­ato-κ(4) O,O′:O′′,O′′′}cobalt(II)]
title Crystal structure of poly[[μ-1,1′-(butane-1,4-di­yl)bis­(1H-benzimidazole)-κ(2) N (3):N (3′)]{μ-4,4′-[1,4-phenyl­enebis(­oxy)]di­ben­zo­ato-κ(4) O,O′:O′′,O′′′}cobalt(II)]
title_full Crystal structure of poly[[μ-1,1′-(butane-1,4-di­yl)bis­(1H-benzimidazole)-κ(2) N (3):N (3′)]{μ-4,4′-[1,4-phenyl­enebis(­oxy)]di­ben­zo­ato-κ(4) O,O′:O′′,O′′′}cobalt(II)]
title_fullStr Crystal structure of poly[[μ-1,1′-(butane-1,4-di­yl)bis­(1H-benzimidazole)-κ(2) N (3):N (3′)]{μ-4,4′-[1,4-phenyl­enebis(­oxy)]di­ben­zo­ato-κ(4) O,O′:O′′,O′′′}cobalt(II)]
title_full_unstemmed Crystal structure of poly[[μ-1,1′-(butane-1,4-di­yl)bis­(1H-benzimidazole)-κ(2) N (3):N (3′)]{μ-4,4′-[1,4-phenyl­enebis(­oxy)]di­ben­zo­ato-κ(4) O,O′:O′′,O′′′}cobalt(II)]
title_short Crystal structure of poly[[μ-1,1′-(butane-1,4-di­yl)bis­(1H-benzimidazole)-κ(2) N (3):N (3′)]{μ-4,4′-[1,4-phenyl­enebis(­oxy)]di­ben­zo­ato-κ(4) O,O′:O′′,O′′′}cobalt(II)]
title_sort crystal structure of poly[[μ-1,1′-(butane-1,4-di­yl)bis­(1h-benzimidazole)-κ(2) n (3):n (3′)]{μ-4,4′-[1,4-phenyl­enebis(­oxy)]di­ben­zo­ato-κ(4) o,o′:o′′,o′′′}cobalt(ii)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459380/
https://www.ncbi.nlm.nih.gov/pubmed/26090167
http://dx.doi.org/10.1107/S2056989015008294
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