A Specific Nucleophilic Ring-Opening Reaction of Aziridines as a Unique Platform for the Construction of Hydrogen Polysulfides Sensors

[Image: see text] A hydrogen polysulfide mediated aziridine ring-opening reaction was discovered. Based on this reaction, a novel H(2)S(n)-specific chemosensor (AP) was developed. AP showed high sensitivity and selectivity for H(2)S(n). Notably, the fluorescent turn-on product (1) exhibited excellen...

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Autores principales: Chen, Wei, Rosser, Ethan W., Zhang, Di, Shi, Wen, Li, Yilin, Dong, Wen-Ji, Ma, Huimin, Hu, Dehong, Xian, Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4460920/
https://www.ncbi.nlm.nih.gov/pubmed/25961957
http://dx.doi.org/10.1021/acs.orglett.5b01194
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author Chen, Wei
Rosser, Ethan W.
Zhang, Di
Shi, Wen
Li, Yilin
Dong, Wen-Ji
Ma, Huimin
Hu, Dehong
Xian, Ming
author_facet Chen, Wei
Rosser, Ethan W.
Zhang, Di
Shi, Wen
Li, Yilin
Dong, Wen-Ji
Ma, Huimin
Hu, Dehong
Xian, Ming
author_sort Chen, Wei
collection PubMed
description [Image: see text] A hydrogen polysulfide mediated aziridine ring-opening reaction was discovered. Based on this reaction, a novel H(2)S(n)-specific chemosensor (AP) was developed. AP showed high sensitivity and selectivity for H(2)S(n). Notably, the fluorescent turn-on product (1) exhibited excellent two-photon photophysical properties, a large Stokes shift, and high solid state luminescent efficiency.
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spelling pubmed-44609202016-05-11 A Specific Nucleophilic Ring-Opening Reaction of Aziridines as a Unique Platform for the Construction of Hydrogen Polysulfides Sensors Chen, Wei Rosser, Ethan W. Zhang, Di Shi, Wen Li, Yilin Dong, Wen-Ji Ma, Huimin Hu, Dehong Xian, Ming Org Lett [Image: see text] A hydrogen polysulfide mediated aziridine ring-opening reaction was discovered. Based on this reaction, a novel H(2)S(n)-specific chemosensor (AP) was developed. AP showed high sensitivity and selectivity for H(2)S(n). Notably, the fluorescent turn-on product (1) exhibited excellent two-photon photophysical properties, a large Stokes shift, and high solid state luminescent efficiency. American Chemical Society 2015-05-11 2015-06-05 /pmc/articles/PMC4460920/ /pubmed/25961957 http://dx.doi.org/10.1021/acs.orglett.5b01194 Text en Copyright © 2015 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Chen, Wei
Rosser, Ethan W.
Zhang, Di
Shi, Wen
Li, Yilin
Dong, Wen-Ji
Ma, Huimin
Hu, Dehong
Xian, Ming
A Specific Nucleophilic Ring-Opening Reaction of Aziridines as a Unique Platform for the Construction of Hydrogen Polysulfides Sensors
title A Specific Nucleophilic Ring-Opening Reaction of Aziridines as a Unique Platform for the Construction of Hydrogen Polysulfides Sensors
title_full A Specific Nucleophilic Ring-Opening Reaction of Aziridines as a Unique Platform for the Construction of Hydrogen Polysulfides Sensors
title_fullStr A Specific Nucleophilic Ring-Opening Reaction of Aziridines as a Unique Platform for the Construction of Hydrogen Polysulfides Sensors
title_full_unstemmed A Specific Nucleophilic Ring-Opening Reaction of Aziridines as a Unique Platform for the Construction of Hydrogen Polysulfides Sensors
title_short A Specific Nucleophilic Ring-Opening Reaction of Aziridines as a Unique Platform for the Construction of Hydrogen Polysulfides Sensors
title_sort specific nucleophilic ring-opening reaction of aziridines as a unique platform for the construction of hydrogen polysulfides sensors
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4460920/
https://www.ncbi.nlm.nih.gov/pubmed/25961957
http://dx.doi.org/10.1021/acs.orglett.5b01194
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