On-Surface Observation of the Formation of Organometallic Complex in a Supramolecular Network

The on-surface formation of organometallic monomers or oligomers, especially in supramolecular network, attracts an extensive interest for chemists and material scientist. In this work, we have investigated metal coordination between zinc (II) phthalocyanine (ZnPc) and 1, 3-di (4-pyridyl) propane (d...

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Autores principales: Li, Yibao, Cheng, Linxiu, Liu, Chunhua, Liu, Wei, Fan, Yulan, Fan, Xiaolin, Zeng, Qingdao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4462016/
https://www.ncbi.nlm.nih.gov/pubmed/26061532
http://dx.doi.org/10.1038/srep10972
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author Li, Yibao
Cheng, Linxiu
Liu, Chunhua
Liu, Wei
Fan, Yulan
Fan, Xiaolin
Zeng, Qingdao
author_facet Li, Yibao
Cheng, Linxiu
Liu, Chunhua
Liu, Wei
Fan, Yulan
Fan, Xiaolin
Zeng, Qingdao
author_sort Li, Yibao
collection PubMed
description The on-surface formation of organometallic monomers or oligomers, especially in supramolecular network, attracts an extensive interest for chemists and material scientist. In this work, we have investigated metal coordination between zinc (II) phthalocyanine (ZnPc) and 1, 3-di (4-pyridyl) propane (dipy-pra) in the 2, 6, 11-tricarboxydecyloxy-3, 7, 10-triundecyloxy triphenylene (asym-TTT) supramolecular template by means of scanning tunneling microscopy (STM) on highly oriented pyrolytic graphite (HOPG) substrate under ambient conditions. The experimental results demonstrate that every two ZnPc molecules in one nano-reactor connect with each other through one dipy-pra molecule by metal-coordination interaction. In this coordinating process, the template of asym-TTT supramolecular networks plays a significant role.
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spelling pubmed-44620162015-06-12 On-Surface Observation of the Formation of Organometallic Complex in a Supramolecular Network Li, Yibao Cheng, Linxiu Liu, Chunhua Liu, Wei Fan, Yulan Fan, Xiaolin Zeng, Qingdao Sci Rep Article The on-surface formation of organometallic monomers or oligomers, especially in supramolecular network, attracts an extensive interest for chemists and material scientist. In this work, we have investigated metal coordination between zinc (II) phthalocyanine (ZnPc) and 1, 3-di (4-pyridyl) propane (dipy-pra) in the 2, 6, 11-tricarboxydecyloxy-3, 7, 10-triundecyloxy triphenylene (asym-TTT) supramolecular template by means of scanning tunneling microscopy (STM) on highly oriented pyrolytic graphite (HOPG) substrate under ambient conditions. The experimental results demonstrate that every two ZnPc molecules in one nano-reactor connect with each other through one dipy-pra molecule by metal-coordination interaction. In this coordinating process, the template of asym-TTT supramolecular networks plays a significant role. Nature Publishing Group 2015-06-10 /pmc/articles/PMC4462016/ /pubmed/26061532 http://dx.doi.org/10.1038/srep10972 Text en Copyright © 2015, Macmillan Publishers Limited http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Li, Yibao
Cheng, Linxiu
Liu, Chunhua
Liu, Wei
Fan, Yulan
Fan, Xiaolin
Zeng, Qingdao
On-Surface Observation of the Formation of Organometallic Complex in a Supramolecular Network
title On-Surface Observation of the Formation of Organometallic Complex in a Supramolecular Network
title_full On-Surface Observation of the Formation of Organometallic Complex in a Supramolecular Network
title_fullStr On-Surface Observation of the Formation of Organometallic Complex in a Supramolecular Network
title_full_unstemmed On-Surface Observation of the Formation of Organometallic Complex in a Supramolecular Network
title_short On-Surface Observation of the Formation of Organometallic Complex in a Supramolecular Network
title_sort on-surface observation of the formation of organometallic complex in a supramolecular network
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4462016/
https://www.ncbi.nlm.nih.gov/pubmed/26061532
http://dx.doi.org/10.1038/srep10972
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