Gelation-driven Dynamic Systemic Resolution: in situ Generation and Self-Selection of an Organogelator

An organogelator was produced and identified from a dynamic imine system, resolved and amplified by selective gelation. The formation of the organogel was monitored in situ by (1)H NMR, showing the existence of multiple reversible reactions operating simultaneously, and the redistribution of the inv...

Descripción completa

Detalles Bibliográficos
Autores principales: Hu, Lei, Zhang, Yang, Ramström, Olof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4462186/
https://www.ncbi.nlm.nih.gov/pubmed/26062041
http://dx.doi.org/10.1038/srep11065
_version_ 1782375628728696832
author Hu, Lei
Zhang, Yang
Ramström, Olof
author_facet Hu, Lei
Zhang, Yang
Ramström, Olof
author_sort Hu, Lei
collection PubMed
description An organogelator was produced and identified from a dynamic imine system, resolved and amplified by selective gelation. The formation of the organogel was monitored in situ by (1)H NMR, showing the existence of multiple reversible reactions operating simultaneously, and the redistribution of the involved species during gelation. The formed organogelator proved effective with a range of organic solvents, including DMSO, toluene, and longer, linear alcohols.
format Online
Article
Text
id pubmed-4462186
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher Nature Publishing Group
record_format MEDLINE/PubMed
spelling pubmed-44621862015-06-16 Gelation-driven Dynamic Systemic Resolution: in situ Generation and Self-Selection of an Organogelator Hu, Lei Zhang, Yang Ramström, Olof Sci Rep Article An organogelator was produced and identified from a dynamic imine system, resolved and amplified by selective gelation. The formation of the organogel was monitored in situ by (1)H NMR, showing the existence of multiple reversible reactions operating simultaneously, and the redistribution of the involved species during gelation. The formed organogelator proved effective with a range of organic solvents, including DMSO, toluene, and longer, linear alcohols. Nature Publishing Group 2015-06-16 /pmc/articles/PMC4462186/ /pubmed/26062041 http://dx.doi.org/10.1038/srep11065 Text en Copyright © 2015, Macmillan Publishers Limited http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Hu, Lei
Zhang, Yang
Ramström, Olof
Gelation-driven Dynamic Systemic Resolution: in situ Generation and Self-Selection of an Organogelator
title Gelation-driven Dynamic Systemic Resolution: in situ Generation and Self-Selection of an Organogelator
title_full Gelation-driven Dynamic Systemic Resolution: in situ Generation and Self-Selection of an Organogelator
title_fullStr Gelation-driven Dynamic Systemic Resolution: in situ Generation and Self-Selection of an Organogelator
title_full_unstemmed Gelation-driven Dynamic Systemic Resolution: in situ Generation and Self-Selection of an Organogelator
title_short Gelation-driven Dynamic Systemic Resolution: in situ Generation and Self-Selection of an Organogelator
title_sort gelation-driven dynamic systemic resolution: in situ generation and self-selection of an organogelator
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4462186/
https://www.ncbi.nlm.nih.gov/pubmed/26062041
http://dx.doi.org/10.1038/srep11065
work_keys_str_mv AT hulei gelationdrivendynamicsystemicresolutioninsitugenerationandselfselectionofanorganogelator
AT zhangyang gelationdrivendynamicsystemicresolutioninsitugenerationandselfselectionofanorganogelator
AT ramstromolof gelationdrivendynamicsystemicresolutioninsitugenerationandselfselectionofanorganogelator

Ejemplares similares