Calculated Third Order Rate Constants for Interpreting the Mechanisms of Hydrolyses of Chloroformates, Carboxylic Acid Halides, Sulfonyl Chlorides and Phosphorochloridates

Hydrolyses of acid derivatives (e.g., carboxylic acid chlorides and fluorides, fluoro- and chloroformates, sulfonyl chlorides, phosphorochloridates, anhydrides) exhibit pseudo-first order kinetics. Reaction mechanisms vary from those involving a cationic intermediate (S(N)1) to concerted S(N)2 proce...

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Detalles Bibliográficos
Autor principal: Bentley, T. William
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4463664/
https://www.ncbi.nlm.nih.gov/pubmed/26006228
http://dx.doi.org/10.3390/ijms160510601

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4463664/
https://www.ncbi.nlm.nih.gov/pubmed/26006228
http://dx.doi.org/10.3390/ijms160510601

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