Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor

A dissymmetric TTF-type electron donor, cyanobenzene-ethylenedithio-tetrathiafulvalene (CNB-EDT-TTF), was obtained in high yield, by a cross-coupling reaction with triethyl phosphite between 2-thioxobenzo[d][1,3]dithiole-5-carbonitrile and 5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-one. This new...

Descripción completa

Detalles Bibliográficos
Autores principales: Oliveira, Sandrina, Belo, Dulce, Santos, Isabel Cordeiro, Rabaça, Sandra, Almeida, Manuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464436/
https://www.ncbi.nlm.nih.gov/pubmed/26124897
http://dx.doi.org/10.3762/bjoc.11.106
_version_ 1782375969648017408
author Oliveira, Sandrina
Belo, Dulce
Santos, Isabel Cordeiro
Rabaça, Sandra
Almeida, Manuel
author_facet Oliveira, Sandrina
Belo, Dulce
Santos, Isabel Cordeiro
Rabaça, Sandra
Almeida, Manuel
author_sort Oliveira, Sandrina
collection PubMed
description A dissymmetric TTF-type electron donor, cyanobenzene-ethylenedithio-tetrathiafulvalene (CNB-EDT-TTF), was obtained in high yield, by a cross-coupling reaction with triethyl phosphite between 2-thioxobenzo[d][1,3]dithiole-5-carbonitrile and 5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-one. This new donor was characterized namely by single crystal X-ray diffraction, cyclic voltammetry, NMR, UV-visible and IR spectroscopy.
format Online
Article
Text
id pubmed-4464436
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher Beilstein-Institut
record_format MEDLINE/PubMed
spelling pubmed-44644362015-06-29 Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor Oliveira, Sandrina Belo, Dulce Santos, Isabel Cordeiro Rabaça, Sandra Almeida, Manuel Beilstein J Org Chem Letter A dissymmetric TTF-type electron donor, cyanobenzene-ethylenedithio-tetrathiafulvalene (CNB-EDT-TTF), was obtained in high yield, by a cross-coupling reaction with triethyl phosphite between 2-thioxobenzo[d][1,3]dithiole-5-carbonitrile and 5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-one. This new donor was characterized namely by single crystal X-ray diffraction, cyclic voltammetry, NMR, UV-visible and IR spectroscopy. Beilstein-Institut 2015-06-03 /pmc/articles/PMC4464436/ /pubmed/26124897 http://dx.doi.org/10.3762/bjoc.11.106 Text en Copyright © 2015, Oliveira et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Oliveira, Sandrina
Belo, Dulce
Santos, Isabel Cordeiro
Rabaça, Sandra
Almeida, Manuel
Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor
title Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor
title_full Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor
title_fullStr Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor
title_full_unstemmed Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor
title_short Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor
title_sort synthesis and characterization of the cyanobenzene-ethylenedithio-ttf donor
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464436/
https://www.ncbi.nlm.nih.gov/pubmed/26124897
http://dx.doi.org/10.3762/bjoc.11.106
work_keys_str_mv AT oliveirasandrina synthesisandcharacterizationofthecyanobenzeneethylenedithiottfdonor
AT belodulce synthesisandcharacterizationofthecyanobenzeneethylenedithiottfdonor
AT santosisabelcordeiro synthesisandcharacterizationofthecyanobenzeneethylenedithiottfdonor
AT rabacasandra synthesisandcharacterizationofthecyanobenzeneethylenedithiottfdonor
AT almeidamanuel synthesisandcharacterizationofthecyanobenzeneethylenedithiottfdonor

Ejemplares similares