Self-assembly of heteroleptic dinuclear metallosupramolecular kites from multivalent ligands via social self-sorting

A Tröger's base-derived racemic bis(1,10-phenanthroline) ligand (rac)-1 and a bis(2,2'-bipyridine) ligand with a central 1,3-diethynylbenzene unit 2 were synthesized. Each of these ligands acts as a multivalent entity for the binding of two copper(I) ions. Upon coordination to the metal io...

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Autores principales: Benkhäuser, Christian, Lützen, Arne
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464459/
https://www.ncbi.nlm.nih.gov/pubmed/26124873
http://dx.doi.org/10.3762/bjoc.11.79
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author Benkhäuser, Christian
Lützen, Arne
author_facet Benkhäuser, Christian
Lützen, Arne
author_sort Benkhäuser, Christian
collection PubMed
description A Tröger's base-derived racemic bis(1,10-phenanthroline) ligand (rac)-1 and a bis(2,2'-bipyridine) ligand with a central 1,3-diethynylbenzene unit 2 were synthesized. Each of these ligands acts as a multivalent entity for the binding of two copper(I) ions. Upon coordination to the metal ions these two ligands undergo selective self-assembly into heteroleptic dinuclear metallosupramolecular kites in a high-fidelity social self-sorting manner as evidenced by NMR spectroscopy and mass spectrometry.
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spelling pubmed-44644592015-06-29 Self-assembly of heteroleptic dinuclear metallosupramolecular kites from multivalent ligands via social self-sorting Benkhäuser, Christian Lützen, Arne Beilstein J Org Chem Full Research Paper A Tröger's base-derived racemic bis(1,10-phenanthroline) ligand (rac)-1 and a bis(2,2'-bipyridine) ligand with a central 1,3-diethynylbenzene unit 2 were synthesized. Each of these ligands acts as a multivalent entity for the binding of two copper(I) ions. Upon coordination to the metal ions these two ligands undergo selective self-assembly into heteroleptic dinuclear metallosupramolecular kites in a high-fidelity social self-sorting manner as evidenced by NMR spectroscopy and mass spectrometry. Beilstein-Institut 2015-05-08 /pmc/articles/PMC4464459/ /pubmed/26124873 http://dx.doi.org/10.3762/bjoc.11.79 Text en Copyright © 2015, Benkhäuser and Lützen https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Benkhäuser, Christian
Lützen, Arne
Self-assembly of heteroleptic dinuclear metallosupramolecular kites from multivalent ligands via social self-sorting
title Self-assembly of heteroleptic dinuclear metallosupramolecular kites from multivalent ligands via social self-sorting
title_full Self-assembly of heteroleptic dinuclear metallosupramolecular kites from multivalent ligands via social self-sorting
title_fullStr Self-assembly of heteroleptic dinuclear metallosupramolecular kites from multivalent ligands via social self-sorting
title_full_unstemmed Self-assembly of heteroleptic dinuclear metallosupramolecular kites from multivalent ligands via social self-sorting
title_short Self-assembly of heteroleptic dinuclear metallosupramolecular kites from multivalent ligands via social self-sorting
title_sort self-assembly of heteroleptic dinuclear metallosupramolecular kites from multivalent ligands via social self-sorting
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464459/
https://www.ncbi.nlm.nih.gov/pubmed/26124873
http://dx.doi.org/10.3762/bjoc.11.79
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