Well-Defined Palladium Nanoparticles Supported on Siliceous Mesocellular Foam as Heterogeneous Catalysts for the Oxidation of Water

Herein, we describe the use of Pd nanoparticles immobilized on an amino-functionalized siliceous mesocellular foam for the catalytic oxidation of H(2)O. The Pd nanocatalyst proved to be capable of mediating the four-electron oxidation of H(2)O to O(2), both chemically and photochemically. The Pd nan...

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Autores principales: Verho, Oscar, Åkermark, Torbjörn, Johnston, Eric V, Gustafson, Karl P J, Tai, Cheuk-W, Svengren, Henrik, Kärkäs, Markus D, Bäckvall, Jan-E, Åkermark, Björn
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464534/
https://www.ncbi.nlm.nih.gov/pubmed/25777800
http://dx.doi.org/10.1002/chem.201406279
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author Verho, Oscar
Åkermark, Torbjörn
Johnston, Eric V
Gustafson, Karl P J
Tai, Cheuk-W
Svengren, Henrik
Kärkäs, Markus D
Bäckvall, Jan-E
Åkermark, Björn
author_facet Verho, Oscar
Åkermark, Torbjörn
Johnston, Eric V
Gustafson, Karl P J
Tai, Cheuk-W
Svengren, Henrik
Kärkäs, Markus D
Bäckvall, Jan-E
Åkermark, Björn
author_sort Verho, Oscar
collection PubMed
description Herein, we describe the use of Pd nanoparticles immobilized on an amino-functionalized siliceous mesocellular foam for the catalytic oxidation of H(2)O. The Pd nanocatalyst proved to be capable of mediating the four-electron oxidation of H(2)O to O(2), both chemically and photochemically. The Pd nanocatalyst is easy to prepare and shows high chemical stability, low leaching, and recyclability. Together with its promising catalytic activity, these features make the Pd nanocatalyst of potential interest for future sustainable solar-fuel production.
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spelling pubmed-44645342015-06-17 Well-Defined Palladium Nanoparticles Supported on Siliceous Mesocellular Foam as Heterogeneous Catalysts for the Oxidation of Water Verho, Oscar Åkermark, Torbjörn Johnston, Eric V Gustafson, Karl P J Tai, Cheuk-W Svengren, Henrik Kärkäs, Markus D Bäckvall, Jan-E Åkermark, Björn Chemistry Full Papers Herein, we describe the use of Pd nanoparticles immobilized on an amino-functionalized siliceous mesocellular foam for the catalytic oxidation of H(2)O. The Pd nanocatalyst proved to be capable of mediating the four-electron oxidation of H(2)O to O(2), both chemically and photochemically. The Pd nanocatalyst is easy to prepare and shows high chemical stability, low leaching, and recyclability. Together with its promising catalytic activity, these features make the Pd nanocatalyst of potential interest for future sustainable solar-fuel production. WILEY-VCH Verlag 2015-04-07 2015-03-16 /pmc/articles/PMC4464534/ /pubmed/25777800 http://dx.doi.org/10.1002/chem.201406279 Text en © 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. http://creativecommons.org/licenses/by/3.0/ This is an open access article under the terms of Creative Commons Attribution NonCommercial-NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.
spellingShingle Full Papers
Verho, Oscar
Åkermark, Torbjörn
Johnston, Eric V
Gustafson, Karl P J
Tai, Cheuk-W
Svengren, Henrik
Kärkäs, Markus D
Bäckvall, Jan-E
Åkermark, Björn
Well-Defined Palladium Nanoparticles Supported on Siliceous Mesocellular Foam as Heterogeneous Catalysts for the Oxidation of Water
title Well-Defined Palladium Nanoparticles Supported on Siliceous Mesocellular Foam as Heterogeneous Catalysts for the Oxidation of Water
title_full Well-Defined Palladium Nanoparticles Supported on Siliceous Mesocellular Foam as Heterogeneous Catalysts for the Oxidation of Water
title_fullStr Well-Defined Palladium Nanoparticles Supported on Siliceous Mesocellular Foam as Heterogeneous Catalysts for the Oxidation of Water
title_full_unstemmed Well-Defined Palladium Nanoparticles Supported on Siliceous Mesocellular Foam as Heterogeneous Catalysts for the Oxidation of Water
title_short Well-Defined Palladium Nanoparticles Supported on Siliceous Mesocellular Foam as Heterogeneous Catalysts for the Oxidation of Water
title_sort well-defined palladium nanoparticles supported on siliceous mesocellular foam as heterogeneous catalysts for the oxidation of water
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464534/
https://www.ncbi.nlm.nih.gov/pubmed/25777800
http://dx.doi.org/10.1002/chem.201406279
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