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Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex**

We report the uranium(VI) carbene imido oxo complex [U(BIPM(TMS))(NMes)(O)(DMAP)(2)] (5, BIPM(TMS)=C(PPh(2)NSiMe(3))(2); Mes=2,4,6-Me(3)C(6)H(2); DMAP=4-(dimethylamino)pyridine) which exhibits the unprecedented arrangement of three formal multiply bonded ligands to one metal center where the coordin...

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Detalles Bibliográficos
Autores principales:	Lu, Erli, Cooper, Oliver J, McMaster, Jonathan, Tuna, Floriana, McInnes, Eric J L, Lewis, William, Blake, Alexander J, Liddle, Stephen T
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	WILEY-VCH Verlag 2014
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464547/ https://www.ncbi.nlm.nih.gov/pubmed/24842784 http://dx.doi.org/10.1002/anie.201403892

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