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Exploring the open-circuit voltage of organic solar cells under low temperature
Open-circuit voltage (V(OC)) in organic solar cells (OSCs) is currently still not well-understood. A generally acceptable view is that V(OC) is mainly determined by the energy level offset between donor and acceptor materials. Recently in ternary blend OSCs, V(OC) is found to be dependent on the ble...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4468816/ https://www.ncbi.nlm.nih.gov/pubmed/26079701 http://dx.doi.org/10.1038/srep11363 |
Sumario: | Open-circuit voltage (V(OC)) in organic solar cells (OSCs) is currently still not well-understood. A generally acceptable view is that V(OC) is mainly determined by the energy level offset between donor and acceptor materials. Recently in ternary blend OSCs, V(OC) is found to be dependent on the blend composition. But contrary to expectation, this dependence is not a simple linear relationship, which adds complications to understanding on V(OC). Here, in order to figure out the origin of V(OC), we performed a series of experiments on both binary and ternary blend OSCs in a wide temperature range from 15 K to 300 K. It is observed that the devices behave like Schottky barrier (SB) diode. By fitting the experimental results with SB diode model, the detailed device parameters of ternary blend OSCs are extracted and it is found that V(OC) is determined by the energetics of organic molecules and metal at the cathode interface, and the inhomogeneity of the SB also play a great role in the origin of V(OC) at low temperatures. This work not only paves the way to deep understanding on the origin of V(OC), but also opens a door to further exploring the general working principle of OSCs. |
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