[Cr(III)(8)M(II)(6)](12+) Coordination Cubes (M(II)=Cu, Co)**

[Cr(III)(8)M(II)(6)](12+) (M(II)=Cu, Co) coordination cubes were constructed from a simple [Cr(III)L(3)] metalloligand and a “naked” M(II) salt. The flexibility in the design proffers the potential to tune the physical properties, as all the constituent parts of the cage can be changed without struc...

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Detalles Bibliográficos
Autores principales: Sanz, Sergio, O'Connor, Helen M, Pineda, Eufemio Moreno, Pedersen, Kasper S, Nichol, Gary S, Mønsted, Ole, Weihe, Høgni, Piligkos, Stergios, McInnes, Eric J L, Lusby, Paul J, Brechin, Euan K
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4471575/
https://www.ncbi.nlm.nih.gov/pubmed/25891167
http://dx.doi.org/10.1002/anie.201501041
Descripción
Sumario:[Cr(III)(8)M(II)(6)](12+) (M(II)=Cu, Co) coordination cubes were constructed from a simple [Cr(III)L(3)] metalloligand and a “naked” M(II) salt. The flexibility in the design proffers the potential to tune the physical properties, as all the constituent parts of the cage can be changed without structural alteration. Computational techniques (known in theoretical nuclear physics as statistical spectroscopy) in tandem with EPR spectroscopy are used to interpret the magnetic behavior.

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