[Cr(III)(8)M(II)(6)](12+) Coordination Cubes (M(II)=Cu, Co)**

[Cr(III)(8)M(II)(6)](12+) (M(II)=Cu, Co) coordination cubes were constructed from a simple [Cr(III)L(3)] metalloligand and a “naked” M(II) salt. The flexibility in the design proffers the potential to tune the physical properties, as all the constituent parts of the cage can be changed without struc...

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Autores principales: Sanz, Sergio, O'Connor, Helen M, Pineda, Eufemio Moreno, Pedersen, Kasper S, Nichol, Gary S, Mønsted, Ole, Weihe, Høgni, Piligkos, Stergios, McInnes, Eric J L, Lusby, Paul J, Brechin, Euan K
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4471575/
https://www.ncbi.nlm.nih.gov/pubmed/25891167
http://dx.doi.org/10.1002/anie.201501041
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author Sanz, Sergio
O'Connor, Helen M
Pineda, Eufemio Moreno
Pedersen, Kasper S
Nichol, Gary S
Mønsted, Ole
Weihe, Høgni
Piligkos, Stergios
McInnes, Eric J L
Lusby, Paul J
Brechin, Euan K
author_facet Sanz, Sergio
O'Connor, Helen M
Pineda, Eufemio Moreno
Pedersen, Kasper S
Nichol, Gary S
Mønsted, Ole
Weihe, Høgni
Piligkos, Stergios
McInnes, Eric J L
Lusby, Paul J
Brechin, Euan K
author_sort Sanz, Sergio
collection PubMed
description [Cr(III)(8)M(II)(6)](12+) (M(II)=Cu, Co) coordination cubes were constructed from a simple [Cr(III)L(3)] metalloligand and a “naked” M(II) salt. The flexibility in the design proffers the potential to tune the physical properties, as all the constituent parts of the cage can be changed without structural alteration. Computational techniques (known in theoretical nuclear physics as statistical spectroscopy) in tandem with EPR spectroscopy are used to interpret the magnetic behavior.
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spelling pubmed-44715752015-06-23 [Cr(III)(8)M(II)(6)](12+) Coordination Cubes (M(II)=Cu, Co)** Sanz, Sergio O'Connor, Helen M Pineda, Eufemio Moreno Pedersen, Kasper S Nichol, Gary S Mønsted, Ole Weihe, Høgni Piligkos, Stergios McInnes, Eric J L Lusby, Paul J Brechin, Euan K Angew Chem Int Ed Engl Communications [Cr(III)(8)M(II)(6)](12+) (M(II)=Cu, Co) coordination cubes were constructed from a simple [Cr(III)L(3)] metalloligand and a “naked” M(II) salt. The flexibility in the design proffers the potential to tune the physical properties, as all the constituent parts of the cage can be changed without structural alteration. Computational techniques (known in theoretical nuclear physics as statistical spectroscopy) in tandem with EPR spectroscopy are used to interpret the magnetic behavior. WILEY-VCH Verlag 2015-06-01 2015-04-17 /pmc/articles/PMC4471575/ /pubmed/25891167 http://dx.doi.org/10.1002/anie.201501041 Text en © 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. http://creativecommons.org/licenses/by-nc-nd/3.0/ This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Sanz, Sergio
O'Connor, Helen M
Pineda, Eufemio Moreno
Pedersen, Kasper S
Nichol, Gary S
Mønsted, Ole
Weihe, Høgni
Piligkos, Stergios
McInnes, Eric J L
Lusby, Paul J
Brechin, Euan K
[Cr(III)(8)M(II)(6)](12+) Coordination Cubes (M(II)=Cu, Co)**
title [Cr(III)(8)M(II)(6)](12+) Coordination Cubes (M(II)=Cu, Co)**
title_full [Cr(III)(8)M(II)(6)](12+) Coordination Cubes (M(II)=Cu, Co)**
title_fullStr [Cr(III)(8)M(II)(6)](12+) Coordination Cubes (M(II)=Cu, Co)**
title_full_unstemmed [Cr(III)(8)M(II)(6)](12+) Coordination Cubes (M(II)=Cu, Co)**
title_short [Cr(III)(8)M(II)(6)](12+) Coordination Cubes (M(II)=Cu, Co)**
title_sort [cr(iii)(8)m(ii)(6)](12+) coordination cubes (m(ii)=cu, co)**
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4471575/
https://www.ncbi.nlm.nih.gov/pubmed/25891167
http://dx.doi.org/10.1002/anie.201501041
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