Mild Deoxygenation of Aromatic Ketones and Aldehydes over Pd/C Using Polymethylhydrosiloxane as the Reducing Agent**

Herein, a practical and mild method for the deoxygenation of a wide range of benzylic aldehydes and ketones is described, which utilizes heterogeneous Pd/C as the catalyst together with the green hydride source, polymethylhydrosiloxane. The developed catalytic protocol is scalable and robust, as exe...

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Detalles Bibliográficos
Autores principales: Volkov, Alexey, Gustafson, Karl P J, Tai, Cheuk-Wai, Verho, Oscar, Bäckvall, Jan-E, Adolfsson, Hans
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4471587/
https://www.ncbi.nlm.nih.gov/pubmed/25728614
http://dx.doi.org/10.1002/anie.201411059

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4471587/
https://www.ncbi.nlm.nih.gov/pubmed/25728614
http://dx.doi.org/10.1002/anie.201411059

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