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Mild Deoxygenation of Aromatic Ketones and Aldehydes over Pd/C Using Polymethylhydrosiloxane as the Reducing Agent**
Herein, a practical and mild method for the deoxygenation of a wide range of benzylic aldehydes and ketones is described, which utilizes heterogeneous Pd/C as the catalyst together with the green hydride source, polymethylhydrosiloxane. The developed catalytic protocol is scalable and robust, as exe...
Autores principales: | Volkov, Alexey, Gustafson, Karl P J, Tai, Cheuk-Wai, Verho, Oscar, Bäckvall, Jan-E, Adolfsson, Hans |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY-VCH Verlag
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4471587/ https://www.ncbi.nlm.nih.gov/pubmed/25728614 http://dx.doi.org/10.1002/anie.201411059 |
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