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Reactivity of Gold Hydrides: O(2) Insertion into the Au–H Bond
[Image: see text] Dioxygen reacts with the gold(I) hydride (IPr)AuH under insertion to give the hydroperoxide (IPr)AuOOH, a long-postulated reaction in gold catalysis and the first demonstration of O(2) activation by Au–H in a well-defined system. Subsequent condensation gave the peroxide (IPr)Au–OO...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4482408/ https://www.ncbi.nlm.nih.gov/pubmed/26146435 http://dx.doi.org/10.1021/om501165z |