Recent XAS studies into Homogeneous metal catalyst in fine chemical and pharmaceutical syntheses

A brief review of studies using X-ray Absorption Spectroscopy (XAS) to investigate homogeneous catalytic reactions in fine chemical and pharmaceutical context since 2010 is presented. The advantages of the techniques over traditional lab-based analytical tools, particularly when NMR spectroscopy fai...

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Detalles Bibliográficos
Autores principales: Sherborne, Grant J, Nguyen, Bao N
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer International Publishing 2015
Materias:
Mini Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4488116/
https://www.ncbi.nlm.nih.gov/pubmed/26140050
http://dx.doi.org/10.1186/s13065-015-0103-6
Descripción
Sumario:A brief review of studies using X-ray Absorption Spectroscopy (XAS) to investigate homogeneous catalytic reactions in fine chemical and pharmaceutical context since 2010 is presented. The advantages of the techniques over traditional lab-based analytical tools, particularly when NMR spectroscopy fails to deliver mechanistic insights, are summarised using these examples. A discussion on the current limitations of the techniques and challenges in the near future is also included. [Figure: see text]

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