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Fundamental differences between glassy dynamics in two and three dimensions

The two-dimensional freezing transition is very different from its three-dimensional counterpart. In contrast, the glass transition is usually assumed to have similar characteristics in two and three dimensions. Using computer simulations, here we show that glassy dynamics in supercooled two- and th...

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Detalles Bibliográficos
Autores principales: Flenner, Elijah, Szamel, Grzegorz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Pub. Group 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4490572/
https://www.ncbi.nlm.nih.gov/pubmed/26067877
http://dx.doi.org/10.1038/ncomms8392
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author Flenner, Elijah
Szamel, Grzegorz
author_facet Flenner, Elijah
Szamel, Grzegorz
author_sort Flenner, Elijah
collection PubMed
description The two-dimensional freezing transition is very different from its three-dimensional counterpart. In contrast, the glass transition is usually assumed to have similar characteristics in two and three dimensions. Using computer simulations, here we show that glassy dynamics in supercooled two- and three-dimensional fluids are fundamentally different. Specifically, transient localization of particles on approaching the glass transition is absent in two dimensions, whereas it is very pronounced in three dimensions. Moreover, the temperature dependence of the relaxation time of orientational correlations is decoupled from that of the translational relaxation time in two dimensions but not in three dimensions. Last, the relationships between the characteristic size of dynamically heterogeneous regions and the relaxation time are very different in two and three dimensions. These results strongly suggest that the glass transition in two dimensions is different than in three dimensions.
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spelling pubmed-44905722015-07-13 Fundamental differences between glassy dynamics in two and three dimensions Flenner, Elijah Szamel, Grzegorz Nat Commun Article The two-dimensional freezing transition is very different from its three-dimensional counterpart. In contrast, the glass transition is usually assumed to have similar characteristics in two and three dimensions. Using computer simulations, here we show that glassy dynamics in supercooled two- and three-dimensional fluids are fundamentally different. Specifically, transient localization of particles on approaching the glass transition is absent in two dimensions, whereas it is very pronounced in three dimensions. Moreover, the temperature dependence of the relaxation time of orientational correlations is decoupled from that of the translational relaxation time in two dimensions but not in three dimensions. Last, the relationships between the characteristic size of dynamically heterogeneous regions and the relaxation time are very different in two and three dimensions. These results strongly suggest that the glass transition in two dimensions is different than in three dimensions. Nature Pub. Group 2015-06-12 /pmc/articles/PMC4490572/ /pubmed/26067877 http://dx.doi.org/10.1038/ncomms8392 Text en Copyright © 2015, Nature Publishing Group, a division of Macmillan Publishers Limited. All Rights Reserved. http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article's Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Flenner, Elijah
Szamel, Grzegorz
Fundamental differences between glassy dynamics in two and three dimensions
title Fundamental differences between glassy dynamics in two and three dimensions
title_full Fundamental differences between glassy dynamics in two and three dimensions
title_fullStr Fundamental differences between glassy dynamics in two and three dimensions
title_full_unstemmed Fundamental differences between glassy dynamics in two and three dimensions
title_short Fundamental differences between glassy dynamics in two and three dimensions
title_sort fundamental differences between glassy dynamics in two and three dimensions
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4490572/
https://www.ncbi.nlm.nih.gov/pubmed/26067877
http://dx.doi.org/10.1038/ncomms8392
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