A General Approach to Sequence-Controlled Polymers Using Macrocyclic Ring Opening Metathesis Polymerization

[Image: see text] A new and general strategy for the synthesis of sequence-defined polymers is described that employs relay metathesis to promote the ring opening polymerization of unstrained macrocyclic structures. Central to this approach is the development of a small molecule “polymerization trig...

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Autores principales: Gutekunst, Will R., Hawker, Craig J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4490773/
https://www.ncbi.nlm.nih.gov/pubmed/26053158
http://dx.doi.org/10.1021/jacs.5b04940
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author Gutekunst, Will R.
Hawker, Craig J.
author_facet Gutekunst, Will R.
Hawker, Craig J.
author_sort Gutekunst, Will R.
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description [Image: see text] A new and general strategy for the synthesis of sequence-defined polymers is described that employs relay metathesis to promote the ring opening polymerization of unstrained macrocyclic structures. Central to this approach is the development of a small molecule “polymerization trigger” which when coupled with a diverse range of sequence-defined units allows for the controlled, directional synthesis of sequence controlled polymers.
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spelling pubmed-44907732015-07-06 A General Approach to Sequence-Controlled Polymers Using Macrocyclic Ring Opening Metathesis Polymerization Gutekunst, Will R. Hawker, Craig J. J Am Chem Soc [Image: see text] A new and general strategy for the synthesis of sequence-defined polymers is described that employs relay metathesis to promote the ring opening polymerization of unstrained macrocyclic structures. Central to this approach is the development of a small molecule “polymerization trigger” which when coupled with a diverse range of sequence-defined units allows for the controlled, directional synthesis of sequence controlled polymers. American Chemical Society 2015-06-08 2015-07-01 /pmc/articles/PMC4490773/ /pubmed/26053158 http://dx.doi.org/10.1021/jacs.5b04940 Text en Copyright © 2015 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Gutekunst, Will R.
Hawker, Craig J.
A General Approach to Sequence-Controlled Polymers Using Macrocyclic Ring Opening Metathesis Polymerization
title A General Approach to Sequence-Controlled Polymers Using Macrocyclic Ring Opening Metathesis Polymerization
title_full A General Approach to Sequence-Controlled Polymers Using Macrocyclic Ring Opening Metathesis Polymerization
title_fullStr A General Approach to Sequence-Controlled Polymers Using Macrocyclic Ring Opening Metathesis Polymerization
title_full_unstemmed A General Approach to Sequence-Controlled Polymers Using Macrocyclic Ring Opening Metathesis Polymerization
title_short A General Approach to Sequence-Controlled Polymers Using Macrocyclic Ring Opening Metathesis Polymerization
title_sort general approach to sequence-controlled polymers using macrocyclic ring opening metathesis polymerization
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4490773/
https://www.ncbi.nlm.nih.gov/pubmed/26053158
http://dx.doi.org/10.1021/jacs.5b04940
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