A coordination polymer with unusual structural features from imidazolylbutyric acid and titanium isopropoxide

ABSTRACT: The coordination polymer [Ti(OiPr)(3)(OOCCH(2)CH(2)CH(2)C(3)N(2)H(3))](n) was prepared from 4-(imidazol-1-yl)butyric acid and titanium isopropoxide. The structure of the compound is remarkable, as the carboxylate group is coordinated in a chelating manner and no dimerization of the Ti(OiPr...

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Detalles Bibliográficos
Autores principales: Czakler, Matthias, Puchberger, Michael, Artner, Christine, Schubert, Ulrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Vienna 2014
Materias:
Original Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4494772/
https://www.ncbi.nlm.nih.gov/pubmed/26166895
http://dx.doi.org/10.1007/s00706-014-1245-2
Descripción
Sumario:ABSTRACT: The coordination polymer [Ti(OiPr)(3)(OOCCH(2)CH(2)CH(2)C(3)N(2)H(3))](n) was prepared from 4-(imidazol-1-yl)butyric acid and titanium isopropoxide. The structure of the compound is remarkable, as the carboxylate group is coordinated in a chelating manner and no dimerization of the Ti(OiPr)(3) groups through OR bridges was observed. GRAPHICAL ABSTRACT: [Image: see text]

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