A coordination polymer with unusual structural features from imidazolylbutyric acid and titanium isopropoxide

ABSTRACT: The coordination polymer [Ti(OiPr)(3)(OOCCH(2)CH(2)CH(2)C(3)N(2)H(3))](n) was prepared from 4-(imidazol-1-yl)butyric acid and titanium isopropoxide. The structure of the compound is remarkable, as the carboxylate group is coordinated in a chelating manner and no dimerization of the Ti(OiPr...

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Detalles Bibliográficos
Autores principales: Czakler, Matthias, Puchberger, Michael, Artner, Christine, Schubert, Ulrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Vienna 2014
Materias:
Original Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4494772/
https://www.ncbi.nlm.nih.gov/pubmed/26166895
http://dx.doi.org/10.1007/s00706-014-1245-2
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author Czakler, Matthias
Puchberger, Michael
Artner, Christine
Schubert, Ulrich
author_facet Czakler, Matthias
Puchberger, Michael
Artner, Christine
Schubert, Ulrich
author_sort Czakler, Matthias
collection PubMed
description ABSTRACT: The coordination polymer [Ti(OiPr)(3)(OOCCH(2)CH(2)CH(2)C(3)N(2)H(3))](n) was prepared from 4-(imidazol-1-yl)butyric acid and titanium isopropoxide. The structure of the compound is remarkable, as the carboxylate group is coordinated in a chelating manner and no dimerization of the Ti(OiPr)(3) groups through OR bridges was observed. GRAPHICAL ABSTRACT: [Image: see text]
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spelling pubmed-44947722015-07-09 A coordination polymer with unusual structural features from imidazolylbutyric acid and titanium isopropoxide Czakler, Matthias Puchberger, Michael Artner, Christine Schubert, Ulrich Monatsh Chem Original Paper ABSTRACT: The coordination polymer [Ti(OiPr)(3)(OOCCH(2)CH(2)CH(2)C(3)N(2)H(3))](n) was prepared from 4-(imidazol-1-yl)butyric acid and titanium isopropoxide. The structure of the compound is remarkable, as the carboxylate group is coordinated in a chelating manner and no dimerization of the Ti(OiPr)(3) groups through OR bridges was observed. GRAPHICAL ABSTRACT: [Image: see text] Springer Vienna 2014-06-05 2014 /pmc/articles/PMC4494772/ /pubmed/26166895 http://dx.doi.org/10.1007/s00706-014-1245-2 Text en © The Author(s) 2014 https://creativecommons.org/licenses/by/4.0/ Open AccessThis article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited.
spellingShingle Original Paper
Czakler, Matthias
Puchberger, Michael
Artner, Christine
Schubert, Ulrich
A coordination polymer with unusual structural features from imidazolylbutyric acid and titanium isopropoxide
title A coordination polymer with unusual structural features from imidazolylbutyric acid and titanium isopropoxide
title_full A coordination polymer with unusual structural features from imidazolylbutyric acid and titanium isopropoxide
title_fullStr A coordination polymer with unusual structural features from imidazolylbutyric acid and titanium isopropoxide
title_full_unstemmed A coordination polymer with unusual structural features from imidazolylbutyric acid and titanium isopropoxide
title_short A coordination polymer with unusual structural features from imidazolylbutyric acid and titanium isopropoxide
title_sort coordination polymer with unusual structural features from imidazolylbutyric acid and titanium isopropoxide
topic Original Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4494772/
https://www.ncbi.nlm.nih.gov/pubmed/26166895
http://dx.doi.org/10.1007/s00706-014-1245-2
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