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Thiol-functionalized anthraquinones: mass spectrometry and electrochemical studies

ABSTRACT: In this work, the synthesis of various thiol-functionalized anthraquinone compounds is presented. The studied compounds were characterized by mass spectrometry and the main fragmentation pathways are discussed. The compounds studied formed stable self-assembled monolayers (SAMs) in the gol...

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Detalles Bibliográficos
Autores principales: Niedziałkowski, Paweł, Ossowski, Tadeusz, Majewski, Radosław, Nowakowska, Zdzisława, Schroeder, Grzegorz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Vienna 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4494848/
https://www.ncbi.nlm.nih.gov/pubmed/26166853
http://dx.doi.org/10.1007/s00706-011-0623-2
Descripción
Sumario:ABSTRACT: In this work, the synthesis of various thiol-functionalized anthraquinone compounds is presented. The studied compounds were characterized by mass spectrometry and the main fragmentation pathways are discussed. The compounds studied formed stable self-assembled monolayers (SAMs) in the gold surface. The parameters for the reduction processes in the gold surface of the studied new anthraquinones were determined by cyclic voltamperometry tests. GRAPHICAL ABSTRACT: [Image: see text]