Kinetics of the [4+2] cycloaddition of cyclopentadiene with (E)-2-aryl-1-cyano-1-nitroethenes

ABSTRACT: The electrophilicity of (E)-2-aryl-1-cyano-1-nitroethenes is not sufficient to induce a zwitterionic course of their [4+2] cycloaddition to cyclopentadiene. The one-step mechanism of these reactions is indicated by the activation parameters, and the substituent and solvent effects on the r...

Descripción completa

Detalles Bibliográficos
Autores principales: Jasiński, Radomir, Kwiatkowska, Magdalena, Barański, Andrzej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Vienna 2012
Materias:
Original Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4495029/
https://www.ncbi.nlm.nih.gov/pubmed/26166865
http://dx.doi.org/10.1007/s00706-012-0735-3
_version_ 1782380188671148032
author Jasiński, Radomir
Kwiatkowska, Magdalena
Barański, Andrzej
author_facet Jasiński, Radomir
Kwiatkowska, Magdalena
Barański, Andrzej
author_sort Jasiński, Radomir
collection PubMed
description ABSTRACT: The electrophilicity of (E)-2-aryl-1-cyano-1-nitroethenes is not sufficient to induce a zwitterionic course of their [4+2] cycloaddition to cyclopentadiene. The one-step mechanism of these reactions is indicated by the activation parameters, and the substituent and solvent effects on the reaction. GRAPHICAL ABSTRACT: [Image: see text]
format Online
Article
Text
id pubmed-4495029
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher Springer Vienna
record_format MEDLINE/PubMed
spelling pubmed-44950292015-07-09 Kinetics of the [4+2] cycloaddition of cyclopentadiene with (E)-2-aryl-1-cyano-1-nitroethenes Jasiński, Radomir Kwiatkowska, Magdalena Barański, Andrzej Monatsh Chem Original Paper ABSTRACT: The electrophilicity of (E)-2-aryl-1-cyano-1-nitroethenes is not sufficient to induce a zwitterionic course of their [4+2] cycloaddition to cyclopentadiene. The one-step mechanism of these reactions is indicated by the activation parameters, and the substituent and solvent effects on the reaction. GRAPHICAL ABSTRACT: [Image: see text] Springer Vienna 2012-03-02 2012 /pmc/articles/PMC4495029/ /pubmed/26166865 http://dx.doi.org/10.1007/s00706-012-0735-3 Text en © The Author(s) 2012 https://creativecommons.org/licenses/by/4.0/ This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited.
spellingShingle Original Paper
Jasiński, Radomir
Kwiatkowska, Magdalena
Barański, Andrzej
Kinetics of the [4+2] cycloaddition of cyclopentadiene with (E)-2-aryl-1-cyano-1-nitroethenes
title Kinetics of the [4+2] cycloaddition of cyclopentadiene with (E)-2-aryl-1-cyano-1-nitroethenes
title_full Kinetics of the [4+2] cycloaddition of cyclopentadiene with (E)-2-aryl-1-cyano-1-nitroethenes
title_fullStr Kinetics of the [4+2] cycloaddition of cyclopentadiene with (E)-2-aryl-1-cyano-1-nitroethenes
title_full_unstemmed Kinetics of the [4+2] cycloaddition of cyclopentadiene with (E)-2-aryl-1-cyano-1-nitroethenes
title_short Kinetics of the [4+2] cycloaddition of cyclopentadiene with (E)-2-aryl-1-cyano-1-nitroethenes
title_sort kinetics of the [4+2] cycloaddition of cyclopentadiene with (e)-2-aryl-1-cyano-1-nitroethenes
topic Original Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4495029/
https://www.ncbi.nlm.nih.gov/pubmed/26166865
http://dx.doi.org/10.1007/s00706-012-0735-3
work_keys_str_mv AT jasinskiradomir kineticsofthe42cycloadditionofcyclopentadienewithe2aryl1cyano1nitroethenes
AT kwiatkowskamagdalena kineticsofthe42cycloadditionofcyclopentadienewithe2aryl1cyano1nitroethenes
AT baranskiandrzej kineticsofthe42cycloadditionofcyclopentadienewithe2aryl1cyano1nitroethenes

Ejemplares similares