Cargando…

Two-Electron Reductive Carbonylation of Terminal Uranium(V) and Uranium(VI) Nitrides to Cyanate by Carbon Monoxide**

Two-electron reductive carbonylation of the uranium(VI) nitride [U(Tren(TIPS))(N)] (2, Tren(TIPS)=N(CH(2)CH(2)NSiiPr(3))(3)) with CO gave the uranium(IV) cyanate [U(Tren(TIPS))(NCO)] (3). KC(8) reduction of 3 resulted in cyanate dissociation to give [U(Tren(TIPS))] (4) and KNCO, or cyanate retention...

Descripción completa

Detalles Bibliográficos
Autores principales:	Cleaves, Peter A, King, David M, Kefalidis, Christos E, Maron, Laurent, Tuna, Floriana, McInnes, Eric J L, McMaster, Jonathan, Lewis, William, Blake, Alexander J, Liddle, Stephen T
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	WILEY-VCH Verlag 2014
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4497608/ https://www.ncbi.nlm.nih.gov/pubmed/25079093 http://dx.doi.org/10.1002/anie.201406203

Ejemplares similares

Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex**
por: Lu, Erli, et al.
Publicado: (2014)

Synthesis and Characterization of an f-Block Terminal Parent Imido [U=NH] Complex: A Masked Uranium(IV) Nitride
por: King, David M., et al.
Publicado: (2014)

Evidence for single metal two electron oxidative addition and reductive elimination at uranium
por: Gardner, Benedict M., et al.
Publicado: (2017)

Thorium- and uranium-azide reductions: a transient dithorium-nitride versus isolable diuranium-nitrides
por: Du, Jingzhen, et al.
Publicado: (2019)

Molecular and electronic structure of terminal and alkali metal-capped uranium(V) nitride complexes
por: King, David M., et al.
Publicado: (2016)

Uranium–nitride chemistry: uranium–uranium electronic communication mediated by nitride bridges
por: King, David M., et al.
Publicado: (2022)

Emergence of comparable covalency in isostructural cerium(iv)– and uranium(iv)–carbon multiple bonds
por: Gregson, Matthew, et al.
Publicado: (2016)

Synthesis, structure, and reactivity of uranium(vi) nitrides
por: Barluzzi, Luciano, et al.
Publicado: (2021)

Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms
por: Chatelain, Lucile, et al.
Publicado: (2020)

Photochemical Synthesis of Transition Metal-Stabilized Uranium(VI) Nitride Complexes
por: Xin, Xiaoqing, et al.
Publicado: (2022)

Evidence for ligand- and solvent-induced disproportionation of uranium(IV)
por: Du, Jingzhen, et al.
Publicado: (2021)

Rare‐Earth‐ and Uranium‐Mesoionic Carbenes: A New Class of f‐Block Carbene Complex Derived from an N‐Heterocyclic Olefin
por: Seed, John A., et al.
Publicado: (2017)

Synthesis and reactivity of a terminal uranium(iv) sulfide supported by siloxide ligands
por: Andrez, Julie, et al.
Publicado: (2016)

Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings
por: Wooles, Ashley J., et al.
Publicado: (2018)

Exceptional uranium(VI)-nitride triple bond covalency from (15)N nuclear magnetic resonance spectroscopy and quantum chemical analysis
por: Du, Jingzhen, et al.
Publicado: (2021)

Evaluating ion exchange resin efficiency and oxidative capacity for the separation of uranium(IV) and uranium(VI)
por: Stoliker, Deborah L, et al.
Publicado: (2013)

Phosphate-Functionalized Polyethylene with High Adsorption of Uranium(VI)
por: Shao, Dadong, et al.
Publicado: (2017)

An Inverted-Sandwich Diuranium μ-η(5):η(5)-Cyclo-P(5) Complex Supported by U-P(5) δ-Bonding**
por: Gardner, Benedict M, et al.
Publicado: (2015)

An Inverted‐Sandwich Diuranium μ‐η(5):η(5)‐Cyclo‐P(5) Complex Supported by U‐P(5) δ‐Bonding
por: Gardner, Benedict M., et al.
Publicado: (2015)

Uranium(iv) terminal hydrosulfido and sulfido complexes: insights into the nature of the uranium–sulfur bond
por: Rosenzweig, Michael W., et al.
Publicado: (2016)

Rapid electrochemical sensor for uranium(vi) assessment in aqueous media
por: Akl, Zeinab F.
Publicado: (2022)

Silyl‐Phosphino‐Carbene Complexes of Uranium(IV)
por: Lu, Erli, et al.
Publicado: (2018)

Intra- and intermolecular interception of a photochemically generated terminal uranium nitride
por: Yadav, Munendra, et al.
Publicado: (2020)

Uranium and thorium complexes of the phosphaethynolate ion
por: Camp, Clément, et al.
Publicado: (2015)

Nitride protonation and NH(3) binding versus N–H bond cleavage in uranium nitrides
por: Keener, Megan, et al.
Publicado: (2021)

The chemistry of uranium
por: Katz, Joseph J, et al.
Publicado: (1951)

The uranium people
por: Libby, Leona Marshall
Publicado: (1979)

Uranium metallurgy
por: Wilkinson, W D
Publicado: (1962)

Uranium enrichment
por: Villani, Stelio
Publicado: (1979)

Uranium XAFS analysis of kidney from rats exposed to uranium
por: Kitahara, Keisuke, et al.
Publicado: (2017)

Uranium : compounds, isotopes and applications /
Publicado: (2009)

Liquid–liquid extraction of uranium(VI) in the system with a membrane contactor
por: Biełuszka, Paweł, et al.
Publicado: (2013)

Experimental and Theoretical Studies on the Adsorption Mechanisms of Uranium (VI) Ions on Chitosan
por: Mishima, Kenji, et al.
Publicado: (2018)

Microscopic and spectroscopic bioassociation study of uranium(VI) with an archaeal Halobacterium isolate
por: Hilpmann, Stephan, et al.
Publicado: (2022)

Uranium (VI) detection in groundwater using a gold nanoparticle/paper-based lateral flow device
por: Quesada-González, Daniel, et al.
Publicado: (2018)

L'uranium et les armes a l'uranium appauvri
por: Roussel, P
Publicado: (2001)

Mesoionic Carbene Complexes of Uranium(IV) and Thorium(IV)
por: Seed, John A., et al.
Publicado: (2022)

[U(III){N(SiMe(2)tBu)(2)}(3)]: A Structurally Authenticated Trigonal Planar Actinide Complex
por: Goodwin, Conrad AP, et al.
Publicado: (2014)

Aquadioxidobis(pentane-2,4-dionato)uranium(VI) pyrazine solvate
por: Kawasaki, Takeshi, et al.
Publicado: (2008)

Plant cell (Brassica napus) response to europium(III) and uranium(VI) exposure
por: Moll, Henry, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_8kpud8487p99vkefa1moa73v1t