Nitrite-Templated Synthesis of Lanthanide-Containing [2]Rotaxanes for Anion Sensing**

The first anion-templated synthesis of a lanthanide-containing interlocked molecule is demonstrated by utilizing a nitrite anion to template initial pseudorotaxane formation. Subsequent stoppering of the interpenetrated assembly allows for the preparation of a lanthanide-functionalized [2]rotaxane i...

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Autores principales: Langton, Matthew J, Blackburn, Octavia A, Lang, Thomas, Faulkner, Stephen, Beer, Paul D
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4497609/
https://www.ncbi.nlm.nih.gov/pubmed/24989322
http://dx.doi.org/10.1002/anie.201405131
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author Langton, Matthew J
Blackburn, Octavia A
Lang, Thomas
Faulkner, Stephen
Beer, Paul D
author_facet Langton, Matthew J
Blackburn, Octavia A
Lang, Thomas
Faulkner, Stephen
Beer, Paul D
author_sort Langton, Matthew J
collection PubMed
description The first anion-templated synthesis of a lanthanide-containing interlocked molecule is demonstrated by utilizing a nitrite anion to template initial pseudorotaxane formation. Subsequent stoppering of the interpenetrated assembly allows for the preparation of a lanthanide-functionalized [2]rotaxane in high yield. Following removal of the nitrite anion template, the europium [2]rotaxane host is demonstrated to recognize and sense fluoride selectively.
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spelling pubmed-44976092015-07-10 Nitrite-Templated Synthesis of Lanthanide-Containing [2]Rotaxanes for Anion Sensing** Langton, Matthew J Blackburn, Octavia A Lang, Thomas Faulkner, Stephen Beer, Paul D Angew Chem Int Ed Engl Communications The first anion-templated synthesis of a lanthanide-containing interlocked molecule is demonstrated by utilizing a nitrite anion to template initial pseudorotaxane formation. Subsequent stoppering of the interpenetrated assembly allows for the preparation of a lanthanide-functionalized [2]rotaxane in high yield. Following removal of the nitrite anion template, the europium [2]rotaxane host is demonstrated to recognize and sense fluoride selectively. WILEY-VCH Verlag 2014-10-20 2014-07-02 /pmc/articles/PMC4497609/ /pubmed/24989322 http://dx.doi.org/10.1002/anie.201405131 Text en © 2014 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. http://creativecommons.org/licenses/by/3.0/ This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Langton, Matthew J
Blackburn, Octavia A
Lang, Thomas
Faulkner, Stephen
Beer, Paul D
Nitrite-Templated Synthesis of Lanthanide-Containing [2]Rotaxanes for Anion Sensing**
title Nitrite-Templated Synthesis of Lanthanide-Containing [2]Rotaxanes for Anion Sensing**
title_full Nitrite-Templated Synthesis of Lanthanide-Containing [2]Rotaxanes for Anion Sensing**
title_fullStr Nitrite-Templated Synthesis of Lanthanide-Containing [2]Rotaxanes for Anion Sensing**
title_full_unstemmed Nitrite-Templated Synthesis of Lanthanide-Containing [2]Rotaxanes for Anion Sensing**
title_short Nitrite-Templated Synthesis of Lanthanide-Containing [2]Rotaxanes for Anion Sensing**
title_sort nitrite-templated synthesis of lanthanide-containing [2]rotaxanes for anion sensing**
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4497609/
https://www.ncbi.nlm.nih.gov/pubmed/24989322
http://dx.doi.org/10.1002/anie.201405131
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