Cargando…

Metal-Free Hydrogenation Catalyzed by an Air-Stable Borane: Use of Solvent as a Frustrated Lewis Base**

In recent years ‘frustrated Lewis pairs’ (FLPs) have been shown to be effective metal-free catalysts for the hydrogenation of many unsaturated substrates. Even so, limited functional-group tolerance restricts the range of solvents in which FLP-mediated reactions can be performed, with all FLP-mediat...

Descripción completa

Detalles Bibliográficos
Autores principales:	Scott, Daniel J, Fuchter, Matthew J, Ashley, Andrew E
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	WILEY-VCH Verlag 2014
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4497615/ https://www.ncbi.nlm.nih.gov/pubmed/25113014 http://dx.doi.org/10.1002/anie.201405531

Ejemplares similares

Facile Protocol for Water-Tolerant “Frustrated Lewis Pair”-Catalyzed Hydrogenation
por: Scott, Daniel J., et al.
Publicado: (2015)

Formation of Nucleophilic Allylboranes from Molecular Hydrogen and Allenes Catalyzed by a Pyridonate Borane that Displays Frustrated Lewis Pair Reactivity
por: Hasenbeck, Max, et al.
Publicado: (2020)

A New Mode of Chemical Reactivity for Metal‐Free Hydrogen Activation by Lewis Acidic Boranes
por: Bennett, Elliot L., et al.
Publicado: (2019)

An Electrochemical Study of Frustrated Lewis Pairs: A Metal-Free Route to Hydrogen Oxidation
por: Lawrence, Elliot J., et al.
Publicado: (2014)

A Strategy to Control the Reactivation of Frustrated Lewis Pairs from Shelf-Stable Carbene Borane Complexes
por: Hoshimoto, Yoichi, et al.
Publicado: (2015)

Geminal bis-borane formation by borane Lewis acid induced cyclopropyl rearrangement and its frustrated Lewis pair reaction with carbon dioxide
por: Liu, Yun-Lin, et al.
Publicado: (2017)

Metal-free electrocatalytic hydrogen oxidation using frustrated Lewis pairs and carbon-based Lewis acids
por: Lawrence, Elliot J., et al.
Publicado: (2016)

Semihydrogenation of Alkynes Catalyzed by a Pyridone Borane Complex: Frustrated Lewis Pair Reactivity and Boron–Ligand Cooperation in Concert
por: Wech, Felix, et al.
Publicado: (2020)

Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”
por: Osipova, Elena S., et al.
Publicado: (2021)

Solid-State NMR Techniques for the Structural Characterization of Cyclic Aggregates Based on Borane–Phosphane Frustrated Lewis Pairs
por: Knitsch, Robert, et al.
Publicado: (2020)

Bi(I)-Catalyzed Transfer-Hydrogenation with Ammonia-Borane
por: Wang, Feng, et al.
Publicado: (2019)

Hydrogen Activation by Frustrated and Not So Frustrated Lewis Pairs Based on Pyramidal Lewis Acid 9-Boratriptycene: A Computational Study
por: Pomogaeva, Anna V., et al.
Publicado: (2022)

Metal-Free Dihydrogen Oxidation by a Borenium Cation: A Combined Electrochemical/Frustrated Lewis Pair Approach**
por: Lawrence, Elliot J, et al.
Publicado: (2014)

Ambiphilic Frustrated Lewis Pair Exhibiting High Robustness and Reversible Water Activation: Towards the Metal-Free Hydrogenation of Carbon Dioxide
por: Rochette, Étienne, et al.
Publicado: (2015)

Parallels between Metal‐Ligand Cooperativity and Frustrated Lewis Pairs
por: Habraken, Evi R. M., et al.
Publicado: (2019)

Understanding and Expanding Zinc Cation/Amine Frustrated Lewis Pair Catalyzed C–H Borylation
por: Grundy, Matthew E., et al.
Publicado: (2023)

Direct Reductive Amination of Carbonyl Compounds Catalyzed by a Moisture Tolerant Tin(IV) Lewis Acid
por: Sapsford, Joshua S., et al.
Publicado: (2018)

Versatile Catalytic Hydrogenation Using A Simple Tin(IV) Lewis Acid
por: Scott, Daniel J., et al.
Publicado: (2016)

Tris(ortho‐carboranyl)borane: An Isolable, Halogen‐Free, Lewis Superacid
por: Akram, Manjur O., et al.
Publicado: (2022)

Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms
por: Chatelain, Lucile, et al.
Publicado: (2020)

Theoretical Study of Hydrogen Production from Ammonia Borane Catalyzed by Metal and Non-Metal Diatom-Doped Cobalt Phosphide
por: Li, Dong-Heng, et al.
Publicado: (2022)

Metal–ligand multiple bonds as frustrated Lewis pairs for C–H functionalization
por: Whited, Matthew T
Publicado: (2012)

Incorporation of Chiral Frustrated Lewis Pair into Metal–Organic Framework with Tailored Microenvironment for Heterogeneous Enantio- and Chemoselective Hydrogenation
por: Zhang, Yin, et al.
Publicado: (2023)

Computational Design of Frustrated Lewis Pairs as a Strategy for Catalytic Hydrogen Activation and Hydrogenation Catalyst
por: Dagnaw, Wasihun Menberu, et al.
Publicado: (2023)

Hydrogenation of Secondary Amides using Phosphane Oxide and Frustrated Lewis Pair Catalysis
por: Köring, Laura, et al.
Publicado: (2021)

Selective Catalytic Frustrated Lewis Pair Hydrogenation of CO(2) in the Presence of Silylhalides
por: Wang, Tongtong, et al.
Publicado: (2021)

A Combined “Electrochemical–Frustrated Lewis Pair” Approach to Hydrogen Activation: Surface Catalytic Effects at Platinum Electrodes
por: Lawrence, Elliot J, et al.
Publicado: (2015)

“Activated Borane”: A Porous Borane Cluster Polymer as an Efficient Lewis Acid-Based Catalyst
por: Lamač, Martin, et al.
Publicado: (2023)

A boron-transfer mechanism mediating the thermally induced revival of frustrated carbene–borane pairs from their shelf-stable adducts
por: Hoshimoto, Yoichi, et al.
Publicado: (2021)

Metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors
por: Oldroyd, Nicola L., et al.
Publicado: (2019)

Magnesocenophane‐Catalyzed Amine Borane Dehydrocoupling
por: Wirtz, Lisa, et al.
Publicado: (2020)

Solid surface frustrated Lewis pair constructed on layered AlOOH for hydrogenation reaction
por: Liu, Shulin, et al.
Publicado: (2022)

Colorimetric Metal‐Free Detection of Carbon Monoxide: Reversible CO Uptake by a BNB Frustrated Lewis Pair
por: Zheng, Xiongfei, et al.
Publicado: (2021)

Alkaline-Earth-Catalyzed Dehydrocoupling of Amines and Boranes
por: Liptrot, David J, et al.
Publicado: (2015)

Remarkably Facile Borane-Promoted, Rhodium-Catalyzed Asymmetric Hydrogenation of Tri- and Tetrasubstituted Alkenes
por: Shoba, Veronika M., et al.
Publicado: (2017)

Dehydration in water: frustrated Lewis pairs directly catalyzed allylization of electron-rich arenes and allyl alcohols
por: Zhang, Hua, et al.
Publicado: (2020)

Solid state frustrated Lewis pair chemistry
por: Wang, Long, et al.
Publicado: (2018)

Reactions of Diethylazo‐Dicarboxylate with Frustrated Lewis Pairs
por: Mandal, Dipendu, et al.
Publicado: (2022)

Single‐Electron Transfer in Frustrated Lewis Pair Chemistry
por: Holtrop, Flip, et al.
Publicado: (2020)

Heterolytic Splitting of Molecular Hydrogen by Frustrated and Classical Lewis Pairs: A Unified Reactivity Concept
por: Skara, Gabriella, et al.
Publicado: (2017)

Cannot write session to /tmp/vufind_sessions/sess_4nr46nsvpiaj3a43fuf69kf848