Modification of Fluorescent Photoinduced Electron Transfer (PET) Sensors/Switches To Produce Molecular Photo-Ionic Triode Action**

The fluorophore-spacer(1)-receptor(1)-spacer(2)-receptor(2) system (where receptor(2) alone is photoredox-inactive) shows ionically tunable proton-induced fluorescence off-on switching, which is reminiscent of thermionic triode behavior. This also represents a new extension to modular switch systems...

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Detalles Bibliográficos
Autores principales: Huxley, Allen J M, Schroeder, Marc, Nimal Gunaratne, H Q, Prasanna de Silva, A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4499248/
https://www.ncbi.nlm.nih.gov/pubmed/24574178
http://dx.doi.org/10.1002/anie.201310939
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author Huxley, Allen J M
Schroeder, Marc
Nimal Gunaratne, H Q
Prasanna de Silva, A
author_facet Huxley, Allen J M
Schroeder, Marc
Nimal Gunaratne, H Q
Prasanna de Silva, A
author_sort Huxley, Allen J M
collection PubMed
description The fluorophore-spacer(1)-receptor(1)-spacer(2)-receptor(2) system (where receptor(2) alone is photoredox-inactive) shows ionically tunable proton-induced fluorescence off-on switching, which is reminiscent of thermionic triode behavior. This also represents a new extension to modular switch systems based on photoinduced electron transfer (PET) towards the emulation of analogue electronic devices.
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spelling pubmed-44992482015-07-16 Modification of Fluorescent Photoinduced Electron Transfer (PET) Sensors/Switches To Produce Molecular Photo-Ionic Triode Action** Huxley, Allen J M Schroeder, Marc Nimal Gunaratne, H Q Prasanna de Silva, A Angew Chem Int Ed Engl Communications The fluorophore-spacer(1)-receptor(1)-spacer(2)-receptor(2) system (where receptor(2) alone is photoredox-inactive) shows ionically tunable proton-induced fluorescence off-on switching, which is reminiscent of thermionic triode behavior. This also represents a new extension to modular switch systems based on photoinduced electron transfer (PET) towards the emulation of analogue electronic devices. WILEY-VCH Verlag 2014-04-01 2014-02-26 /pmc/articles/PMC4499248/ /pubmed/24574178 http://dx.doi.org/10.1002/anie.201310939 Text en © 2014 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. http://creativecommons.org/licenses/by/3.0/ This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Huxley, Allen J M
Schroeder, Marc
Nimal Gunaratne, H Q
Prasanna de Silva, A
Modification of Fluorescent Photoinduced Electron Transfer (PET) Sensors/Switches To Produce Molecular Photo-Ionic Triode Action**
title Modification of Fluorescent Photoinduced Electron Transfer (PET) Sensors/Switches To Produce Molecular Photo-Ionic Triode Action**
title_full Modification of Fluorescent Photoinduced Electron Transfer (PET) Sensors/Switches To Produce Molecular Photo-Ionic Triode Action**
title_fullStr Modification of Fluorescent Photoinduced Electron Transfer (PET) Sensors/Switches To Produce Molecular Photo-Ionic Triode Action**
title_full_unstemmed Modification of Fluorescent Photoinduced Electron Transfer (PET) Sensors/Switches To Produce Molecular Photo-Ionic Triode Action**
title_short Modification of Fluorescent Photoinduced Electron Transfer (PET) Sensors/Switches To Produce Molecular Photo-Ionic Triode Action**
title_sort modification of fluorescent photoinduced electron transfer (pet) sensors/switches to produce molecular photo-ionic triode action**
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4499248/
https://www.ncbi.nlm.nih.gov/pubmed/24574178
http://dx.doi.org/10.1002/anie.201310939
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