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A Nano-sized Supramolecule Beyond the Fullerene Topology**

The reaction of [Cp(Bn)Fe(η(5)-P(5))] (1) (Cp(Bn)=η(5)-C(5)(CH(2)Ph)(5)) with CuI selectively yields a novel spherical supramolecule (CH(2)Cl(2))(3.4)@[(Cp(Bn)FeP(5))(12){CuI}(54)(MeCN)(1.46)] (2) showing a linkage of the scaffold atoms which is beyond the Fullerene topology. Its extended CuI framew...

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Autores principales: Dielmann, Fabian, Heindl, Claudia, Hastreiter, Florian, Peresypkina, Eugenia V, Virovets, Alexander V, Gschwind, Ruth M, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4501309/
https://www.ncbi.nlm.nih.gov/pubmed/25288480
http://dx.doi.org/10.1002/anie.201407120
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author Dielmann, Fabian
Heindl, Claudia
Hastreiter, Florian
Peresypkina, Eugenia V
Virovets, Alexander V
Gschwind, Ruth M
Scheer, Manfred
author_facet Dielmann, Fabian
Heindl, Claudia
Hastreiter, Florian
Peresypkina, Eugenia V
Virovets, Alexander V
Gschwind, Ruth M
Scheer, Manfred
author_sort Dielmann, Fabian
collection PubMed
description The reaction of [Cp(Bn)Fe(η(5)-P(5))] (1) (Cp(Bn)=η(5)-C(5)(CH(2)Ph)(5)) with CuI selectively yields a novel spherical supramolecule (CH(2)Cl(2))(3.4)@[(Cp(Bn)FeP(5))(12){CuI}(54)(MeCN)(1.46)] (2) showing a linkage of the scaffold atoms which is beyond the Fullerene topology. Its extended CuI framework reveals an outer diameter of 3.7 nm—a size that has not been reached before using five-fold symmetric building blocks. Furthermore, 2 shows a remarkable solubility in CH(2)Cl(2), and NMR spectroscopy reveals that the scaffold of the supramolecule remains intact in solution. In addition, a novel 2D polymer [{Cp(Bn)Fe(η(5)-P(5))}(2){Cu(6)(μ-I)(2)(μ(3)-I)(4)}](n) (3) with an uncommon structural motif was isolated. Its formation can be avoided by using a large excess of CuI in the reaction with 1.
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spelling pubmed-45013092015-07-21 A Nano-sized Supramolecule Beyond the Fullerene Topology** Dielmann, Fabian Heindl, Claudia Hastreiter, Florian Peresypkina, Eugenia V Virovets, Alexander V Gschwind, Ruth M Scheer, Manfred Angew Chem Int Ed Engl Communications The reaction of [Cp(Bn)Fe(η(5)-P(5))] (1) (Cp(Bn)=η(5)-C(5)(CH(2)Ph)(5)) with CuI selectively yields a novel spherical supramolecule (CH(2)Cl(2))(3.4)@[(Cp(Bn)FeP(5))(12){CuI}(54)(MeCN)(1.46)] (2) showing a linkage of the scaffold atoms which is beyond the Fullerene topology. Its extended CuI framework reveals an outer diameter of 3.7 nm—a size that has not been reached before using five-fold symmetric building blocks. Furthermore, 2 shows a remarkable solubility in CH(2)Cl(2), and NMR spectroscopy reveals that the scaffold of the supramolecule remains intact in solution. In addition, a novel 2D polymer [{Cp(Bn)Fe(η(5)-P(5))}(2){Cu(6)(μ-I)(2)(μ(3)-I)(4)}](n) (3) with an uncommon structural motif was isolated. Its formation can be avoided by using a large excess of CuI in the reaction with 1. WILEY-VCH Verlag 2014-12-01 2014-10-06 /pmc/articles/PMC4501309/ /pubmed/25288480 http://dx.doi.org/10.1002/anie.201407120 Text en © 2014 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. http://creativecommons.org/licenses/by/3.0/ This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Dielmann, Fabian
Heindl, Claudia
Hastreiter, Florian
Peresypkina, Eugenia V
Virovets, Alexander V
Gschwind, Ruth M
Scheer, Manfred
A Nano-sized Supramolecule Beyond the Fullerene Topology**
title A Nano-sized Supramolecule Beyond the Fullerene Topology**
title_full A Nano-sized Supramolecule Beyond the Fullerene Topology**
title_fullStr A Nano-sized Supramolecule Beyond the Fullerene Topology**
title_full_unstemmed A Nano-sized Supramolecule Beyond the Fullerene Topology**
title_short A Nano-sized Supramolecule Beyond the Fullerene Topology**
title_sort nano-sized supramolecule beyond the fullerene topology**
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4501309/
https://www.ncbi.nlm.nih.gov/pubmed/25288480
http://dx.doi.org/10.1002/anie.201407120
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