Selective Formation of Trimethylene Carbonate (TMC): Atmospheric Pressure Carbon Dioxide Utilization

Carbon dioxide utilisation (CDU) is currently gaining increased interest due to the abundance of CO(2) and its possible application as a C(1) building block. We herein report the first example of atmospheric pressure carbon dioxide incorporation into oxetane to selectively form trimethylene carbonat...

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Detalles Bibliográficos
Autores principales: Buckley, Benjamin R, Patel, Anish P, Wijayantha, K G Upul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Short Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4502766/
https://www.ncbi.nlm.nih.gov/pubmed/26213485
http://dx.doi.org/10.1002/ejoc.201403385
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author Buckley, Benjamin R
Patel, Anish P
Wijayantha, K G Upul
author_facet Buckley, Benjamin R
Patel, Anish P
Wijayantha, K G Upul
author_sort Buckley, Benjamin R
collection PubMed
description Carbon dioxide utilisation (CDU) is currently gaining increased interest due to the abundance of CO(2) and its possible application as a C(1) building block. We herein report the first example of atmospheric pressure carbon dioxide incorporation into oxetane to selectively form trimethylene carbonate (TMC), which is a significant challenge as TMC is thermodynamically less favoured than its corresponding co-polymer.
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spelling pubmed-45027662015-07-22 Selective Formation of Trimethylene Carbonate (TMC): Atmospheric Pressure Carbon Dioxide Utilization Buckley, Benjamin R Patel, Anish P Wijayantha, K G Upul European J Org Chem Short Communications Carbon dioxide utilisation (CDU) is currently gaining increased interest due to the abundance of CO(2) and its possible application as a C(1) building block. We herein report the first example of atmospheric pressure carbon dioxide incorporation into oxetane to selectively form trimethylene carbonate (TMC), which is a significant challenge as TMC is thermodynamically less favoured than its corresponding co-polymer. WILEY-VCH Verlag 2015-01 2014-12-10 /pmc/articles/PMC4502766/ /pubmed/26213485 http://dx.doi.org/10.1002/ejoc.201403385 Text en Copyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
spellingShingle Short Communications
Buckley, Benjamin R
Patel, Anish P
Wijayantha, K G Upul
Selective Formation of Trimethylene Carbonate (TMC): Atmospheric Pressure Carbon Dioxide Utilization
title Selective Formation of Trimethylene Carbonate (TMC): Atmospheric Pressure Carbon Dioxide Utilization
title_full Selective Formation of Trimethylene Carbonate (TMC): Atmospheric Pressure Carbon Dioxide Utilization
title_fullStr Selective Formation of Trimethylene Carbonate (TMC): Atmospheric Pressure Carbon Dioxide Utilization
title_full_unstemmed Selective Formation of Trimethylene Carbonate (TMC): Atmospheric Pressure Carbon Dioxide Utilization
title_short Selective Formation of Trimethylene Carbonate (TMC): Atmospheric Pressure Carbon Dioxide Utilization
title_sort selective formation of trimethylene carbonate (tmc): atmospheric pressure carbon dioxide utilization
topic Short Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4502766/
https://www.ncbi.nlm.nih.gov/pubmed/26213485
http://dx.doi.org/10.1002/ejoc.201403385
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AT patelanishp selectiveformationoftrimethylenecarbonatetmcatmosphericpressurecarbondioxideutilization
AT wijayanthakgupul selectiveformationoftrimethylenecarbonatetmcatmosphericpressurecarbondioxideutilization

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