Palladium-Catalyzed Direct C=H Functionalization of Benzoquinone**

A direct Pd-catalyzed C=H functionalization of benzoquinone (BQ) can be controlled to give either mono- or disubstituted BQ, including the installation of two different groups in a one-pot procedure. BQ can now be directly functionalized with aryl, heteroaryl, cycloalkyl, and cycloalkene groups and,...

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Detalles Bibliográficos
Autores principales: Walker, Sarah E, Jordan-Hore, James A, Johnson, David G, Macgregor, Stuart A, Lee, Ai-Lan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4502976/
https://www.ncbi.nlm.nih.gov/pubmed/25302965
http://dx.doi.org/10.1002/anie.201408054
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author Walker, Sarah E
Jordan-Hore, James A
Johnson, David G
Macgregor, Stuart A
Lee, Ai-Lan
author_facet Walker, Sarah E
Jordan-Hore, James A
Johnson, David G
Macgregor, Stuart A
Lee, Ai-Lan
author_sort Walker, Sarah E
collection PubMed
description A direct Pd-catalyzed C=H functionalization of benzoquinone (BQ) can be controlled to give either mono- or disubstituted BQ, including the installation of two different groups in a one-pot procedure. BQ can now be directly functionalized with aryl, heteroaryl, cycloalkyl, and cycloalkene groups and, moreover, the reaction is conducted in environmentally benign water or acetone as solvents.
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spelling pubmed-45029762015-07-22 Palladium-Catalyzed Direct C=H Functionalization of Benzoquinone** Walker, Sarah E Jordan-Hore, James A Johnson, David G Macgregor, Stuart A Lee, Ai-Lan Angew Chem Int Ed Engl Communications A direct Pd-catalyzed C=H functionalization of benzoquinone (BQ) can be controlled to give either mono- or disubstituted BQ, including the installation of two different groups in a one-pot procedure. BQ can now be directly functionalized with aryl, heteroaryl, cycloalkyl, and cycloalkene groups and, moreover, the reaction is conducted in environmentally benign water or acetone as solvents. WILEY-VCH Verlag 2014-12-08 2014-10-10 /pmc/articles/PMC4502976/ /pubmed/25302965 http://dx.doi.org/10.1002/anie.201408054 Text en © 2014 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. http://creativecommons.org/licenses/by/3.0/ This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Walker, Sarah E
Jordan-Hore, James A
Johnson, David G
Macgregor, Stuart A
Lee, Ai-Lan
Palladium-Catalyzed Direct C=H Functionalization of Benzoquinone**
title Palladium-Catalyzed Direct C=H Functionalization of Benzoquinone**
title_full Palladium-Catalyzed Direct C=H Functionalization of Benzoquinone**
title_fullStr Palladium-Catalyzed Direct C=H Functionalization of Benzoquinone**
title_full_unstemmed Palladium-Catalyzed Direct C=H Functionalization of Benzoquinone**
title_short Palladium-Catalyzed Direct C=H Functionalization of Benzoquinone**
title_sort palladium-catalyzed direct c=h functionalization of benzoquinone**
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4502976/
https://www.ncbi.nlm.nih.gov/pubmed/25302965
http://dx.doi.org/10.1002/anie.201408054
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