Novel carbocationic rearrangements of 1-styrylpropargyl alcohols

The dehydration and subsequent cyclization reactions of 1-styrylpropargyl alcohols was examined. In the course of these studies, numerous scaffolds were synthesized, including a furan, a cyclopentenone, an acyclic enone and even a naphthalenone. The diversity of these structural motifs lies in novel...

Descripción completa

Detalles Bibliográficos
Autores principales: Basmadjian, Christine, Zhang, Fan, Désaubry, Laurent
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4505300/
https://www.ncbi.nlm.nih.gov/pubmed/26199656
http://dx.doi.org/10.3762/bjoc.11.114
_version_ 1782381561720602624
author Basmadjian, Christine
Zhang, Fan
Désaubry, Laurent
author_facet Basmadjian, Christine
Zhang, Fan
Désaubry, Laurent
author_sort Basmadjian, Christine
collection PubMed
description The dehydration and subsequent cyclization reactions of 1-styrylpropargyl alcohols was examined. In the course of these studies, numerous scaffolds were synthesized, including a furan, a cyclopentenone, an acyclic enone and even a naphthalenone. The diversity of these structural motifs lies in novel cascades of reactions originating from a common carbocationic manifold.
format Online
Article
Text
id pubmed-4505300
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher Beilstein-Institut
record_format MEDLINE/PubMed
spelling pubmed-45053002015-07-21 Novel carbocationic rearrangements of 1-styrylpropargyl alcohols Basmadjian, Christine Zhang, Fan Désaubry, Laurent Beilstein J Org Chem Full Research Paper The dehydration and subsequent cyclization reactions of 1-styrylpropargyl alcohols was examined. In the course of these studies, numerous scaffolds were synthesized, including a furan, a cyclopentenone, an acyclic enone and even a naphthalenone. The diversity of these structural motifs lies in novel cascades of reactions originating from a common carbocationic manifold. Beilstein-Institut 2015-06-15 /pmc/articles/PMC4505300/ /pubmed/26199656 http://dx.doi.org/10.3762/bjoc.11.114 Text en Copyright © 2015, Basmadjian et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Basmadjian, Christine
Zhang, Fan
Désaubry, Laurent
Novel carbocationic rearrangements of 1-styrylpropargyl alcohols
title Novel carbocationic rearrangements of 1-styrylpropargyl alcohols
title_full Novel carbocationic rearrangements of 1-styrylpropargyl alcohols
title_fullStr Novel carbocationic rearrangements of 1-styrylpropargyl alcohols
title_full_unstemmed Novel carbocationic rearrangements of 1-styrylpropargyl alcohols
title_short Novel carbocationic rearrangements of 1-styrylpropargyl alcohols
title_sort novel carbocationic rearrangements of 1-styrylpropargyl alcohols
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4505300/
https://www.ncbi.nlm.nih.gov/pubmed/26199656
http://dx.doi.org/10.3762/bjoc.11.114
work_keys_str_mv AT basmadjianchristine novelcarbocationicrearrangementsof1styrylpropargylalcohols
AT zhangfan novelcarbocationicrearrangementsof1styrylpropargylalcohols
AT desaubrylaurent novelcarbocationicrearrangementsof1styrylpropargylalcohols

Ejemplares similares