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Formation and Properties of a Bicyclic Silylated Digermene

In the presence of PMe(3) or N-heterocyclic carbenes, the reaction of oligosilanylene dianions with GeCl(2)⋅dioxane gives germylene–base adducts. After base abstraction, the free germylenes can dimerize by formation of a digermene. An electrochemical and theoretical study of a bicyclic tetrasilylate...

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Detalles Bibliográficos
Autores principales:	Hlina, Johann, Baumgartner, Judith, Marschner, Christoph, Albers, Lena, Müller, Thomas, Jouikov, Viatcheslav V
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	WILEY-VCH Verlag 2014
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4506559/ https://www.ncbi.nlm.nih.gov/pubmed/24981992 http://dx.doi.org/10.1002/chem.201402785

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