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Modular Access to Substituted Azocanes via a Rhodium-Catalyzed Cycloaddition–Fragmentation Strategy

[Image: see text] A short entry to substituted azocanes by a Rh-catalyzed cycloaddition–fragmentation process is described. Specifically, exposure of diverse N-cyclopropylacrylamides to phosphine-ligated cationic Rh(I) catalyst systems under a CO atmosphere enables the directed generation of rhodacy...

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Detalles Bibliográficos
Autores principales: Shaw, Megan H., Croft, Rosemary A., Whittingham, William G., Bower, John F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4508204/
https://www.ncbi.nlm.nih.gov/pubmed/26090897
http://dx.doi.org/10.1021/jacs.5b05215