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Data on electrical properties of nickel modified potassium polytitanates compacted powders

Potassium polytitanates are new promising type of ferroelectric ceramic materials with high ionic conductivity, highly polarizable structure and extremely high permittivity. Its structure is formed by [TiO(6)] octahedral units to layers with mobile potassium and hydroxonium ions in-between. The trea...

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Detalles Bibliográficos
Autores principales: Goffman, V.G., Gorokhovsky, A.V., Gorshkov, N.V., Fedorov, F.S., Tretychenko, E.V., Sevrugin, A.V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4510451/
https://www.ncbi.nlm.nih.gov/pubmed/26217788
http://dx.doi.org/10.1016/j.dib.2015.05.010
Descripción
Sumario:Potassium polytitanates are new promising type of ferroelectric ceramic materials with high ionic conductivity, highly polarizable structure and extremely high permittivity. Its structure is formed by [TiO(6)] octahedral units to layers with mobile potassium and hydroxonium ions in-between. The treatment in solutions containing nickel ions allows forming heterostructured materials which consist of potassium polytitanate particles intercalated by Ni(2+) ions and/or decorated by nickel oxides NiO(x). This modification route is fully dependant on solution pH, i.e. in acidic solutions the intercalation process prevails, in alkaline solutions potassium polytitanate is mostly decorated by the oxides. Therefore, electronic structure and electrical properties can be regulated depending on modification conditions, pH and ions concentration. Here we report the data on electric properties of potassium titanate modified in nickel sulfate solutions at different pH.