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Synthetic Active Site Model of the [NiFeSe] Hydrogenase

A dinuclear synthetic model of the [NiFeSe] hydrogenase active site and a structural, spectroscopic and electrochemical analysis of this complex is reported. [NiFe(‘S(2)Se(2)’)(CO)(3)] (H(2)‘S(2)Se(2)’=1,2-bis(2-thiabutyl-3,3-dimethyl-4-selenol)benzene) has been synthesized by reacting the nickel se...

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Detalles Bibliográficos
Autores principales:	Wombwell, Claire, Reisner, Erwin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	WILEY-VCH Verlag 2015
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4510704/ https://www.ncbi.nlm.nih.gov/pubmed/25847470 http://dx.doi.org/10.1002/chem.201500311

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