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Water Structure Recovery in Chaotropic Anion Recognition: High-Affinity Binding of Dodecaborate Clusters to γ-Cyclodextrin**
Dodecaborate anions of the type B(12)X(12)(2−) and B(12)X(11)Y(2−) (X=H, Cl, Br, I and Y=OH, SH, NH(3)(+), NR(3)(+)) form strong (K(a) up to 10(6) L mol(−1), for B(12)Br(12)(2−)) inclusion complexes with γ-cyclodextrin (γ-CD). The micromolar affinities reached are the highest known for this native C...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
WILEY-VCH Verlag
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4510780/ https://www.ncbi.nlm.nih.gov/pubmed/25951349 http://dx.doi.org/10.1002/anie.201412485 |