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A Molecular Nanotube with Three-Dimensional π-Conjugation**
A π-conjugated twelve-porphyrin tube is synthesized in 32 % yield by a template-directed coupling reaction that joins together six porphyrin dimers, forming twelve new C=C bonds. The nanotube has two bound templates, enclosing an internal volume of approximately 4.5 nm(3). Its UV/Vis/NIR absorption...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY-VCH Verlag
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4510782/ https://www.ncbi.nlm.nih.gov/pubmed/25950655 http://dx.doi.org/10.1002/anie.201502735 |